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Assertion: Hydrazine is a neutral ligand...

Assertion: Hydrazine is a neutral ligand.
Reason: It has two N as donor atoms and behaves as a chelating ligand.

A

If assertion is true but the reason is false

B

If assertion is false but reason is true

C

If both assertion and reason are true and the reason is the correct explanation of assertion

D

If both assertion and reason are true but reason is not the correct explanation of assertion

Text Solution

AI Generated Solution

The correct Answer is:
**Step-by-Step Solution:** 1. **Understanding the Assertion:** - The assertion states that hydrazine is a neutral ligand. - Hydrazine (N2H4) does not carry any positive or negative charge, which makes it a neutral ligand. 2. **Analyzing the Reason:** - The reason provided states that hydrazine has two nitrogen atoms as donor atoms and behaves as a chelating ligand. - It is true that hydrazine has two nitrogen atoms that can act as donor atoms. 3. **Evaluating Chelating Ability:** - A chelating ligand is one that can form multiple bonds with a metal ion, typically resulting in the formation of a ring structure. - For hydrazine to act as a chelating ligand, it would need to form a stable ring with the metal ion. 4. **Stability of the Chelate:** - If hydrazine were to chelate a metal ion, it would form a three-membered ring (due to its two nitrogen donor atoms and the metal). - Three-membered rings are generally unstable due to angle strain, making it unfavorable for hydrazine to act as a chelating ligand. 5. **Conclusion:** - The assertion is correct: hydrazine is a neutral ligand. - The reason is incorrect: hydrazine does not behave as a chelating ligand because the chelate formed would be unstable. 6. **Final Answer:** - The correct answer is that the assertion is true, but the reason is false. ---

**Step-by-Step Solution:** 1. **Understanding the Assertion:** - The assertion states that hydrazine is a neutral ligand. - Hydrazine (N2H4) does not carry any positive or negative charge, which makes it a neutral ligand. 2. **Analyzing the Reason:** - The reason provided states that hydrazine has two nitrogen atoms as donor atoms and behaves as a chelating ligand. ...
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