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FeCr(2)O(4)+NaOH+"air" to (A)+Fe(2)O(3) ...

`FeCr_(2)O_(4)+NaOH+"air" to (A)+Fe_(2)O_(3)`
`(A)+(B) to Na_(2)Cr_(2)O_(7)`
`Na_(2)Cr_(2)O_(7)+X overset(Delta)to Cr_(2)O_(3)`
`Cr_(2)O_(3)+Y overset(Delta)to Cr`
(X) and (Y) are :

A

C and Al

B

Al and C

C

C in both

D

Al in both

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given problem step by step, we will analyze the reactions and identify the compounds involved. ### Step 1: Identify the reaction of FeCr₂O₄ with NaOH and air The first reaction involves FeCr₂O₄ (chromite) reacting with NaOH in the presence of air. This reaction leads to the formation of sodium chromate (Na₂CrO₄) and iron(III) oxide (Fe₂O₃). **Reaction:** \[ \text{FeCr}_2\text{O}_4 + \text{NaOH} + \text{air} \rightarrow \text{Na}_2\text{CrO}_4 + \text{Fe}_2\text{O}_3 \] **Hint:** Look for the oxidation states of chromium and iron in the products to confirm the formation of Na₂CrO₄ and Fe₂O₃. ### Step 2: Identify compound (A) and (B) From the above reaction, we can identify: - (A) = Na₂CrO₄ - (B) = Fe₂O₃ ### Step 3: Reaction of (A) and (B) to form Na₂Cr₂O₇ Next, we combine (A) with (B) to form sodium dichromate (Na₂Cr₂O₇). The reaction typically involves the addition of sulfuric acid (H₂SO₄) to sodium chromate. **Reaction:** \[ \text{Na}_2\text{CrO}_4 + \text{H}_2\text{SO}_4 \rightarrow \text{Na}_2\text{Cr}_2\text{O}_7 + \text{H}_2\text{O} \] **Hint:** Consider the role of sulfuric acid in converting chromate to dichromate. ### Step 4: Identify (X) in the reaction of Na₂Cr₂O₇ to Cr₂O₃ In the next step, Na₂Cr₂O₇ reacts with a reducing agent (X) to produce chromium(III) oxide (Cr₂O₃). A common reducing agent used in this context is carbon (C). **Reaction:** \[ \text{Na}_2\text{Cr}_2\text{O}_7 + \text{C} \overset{\Delta}{\rightarrow} \text{Cr}_2\text{O}_3 + \text{Na}_2\text{O} + \text{CO}_2 \] **Hint:** Look for a reducing agent that can convert Cr from +6 to +3 oxidation state. ### Step 5: Identify (Y) in the reaction of Cr₂O₃ to Cr Finally, Cr₂O₃ can be reduced to chromium (Cr) using aluminum (Al) as a reducing agent. **Reaction:** \[ \text{Cr}_2\text{O}_3 + \text{Al} \overset{\Delta}{\rightarrow} \text{Cr} + \text{Al}_2\text{O}_3 \] **Hint:** Think about the thermodynamic feasibility of reducing Cr₂O₃ with a metal. ### Conclusion Based on the above reactions, we can conclude: - (X) = Carbon (C) - (Y) = Aluminum (Al) Thus, the final answer is: - (X) = Carbon - (Y) = Aluminum
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FeCr_(2)O_(4)+NaOH+"air" to (A)+Fe_(2)O_(3) (A)+(B) to Na_(2)Cr_(2)O_(7) Na_(2)Cr_(2)O_(7)+X overset(Delta)to Cr_(2)O_(3) Cr_(2)O_(3)+Y overset(Delta)to Cr Compound (A) and (B) are :

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