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Assertion: K^(+) and NH(4)^(+) ions have...

Assertion: `K^(+) and NH_(4)^(+)` ions have many similarities in their test
Reason: Radius of `K^(+)` is almost equal to radius `NH_(4)^(+)`

A

If both assertion and reason are true and the reason is the correct explanation of assertion

B

If both assertion and reason are true and the reason is not the correct explanation of assertion

C

If assertion is false but reason is true

D

If assertion is true but the reason is false

Text Solution

Verified by Experts

The correct Answer is:
A

Ionic radius of `NH_(4)^(+)` is almost equal to ionic radius of `K^(+)`
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Assertion : Formation of PH_(4)^(+) ion is relatively difficult in comparison to NH_(4)^(+) ion. Reason : Lone pair of phosphorus atom in PH_(3) resides in stereochemically inactive pure s-orbital.

Assertion : Formation of PH_(4)^(+) ion is relatively difficult in comparison to NH_(4)^(+) ion. Reason : Lone pair of phosphorus atom in PH_(3) resides in stereochemically inactive pure s-orbital.

The density of NH_(4)Cl is 1.534 g cm^(-3) . It crystallizes in the CsCl lattice. a. Calculate the length of the length of the edge of NH_(4)Cl unit cell. b. Calculate the shortest distance between a NH_(4)^(o+) ion and a Cl^(ɵ) ion. c. Calculate the radius of NH_(4)^(o+) ion if the radius of the Cl^(ɵ) ion is 181 pm

Assertion (A): On addition of NH_(4)CI to NH_(4)OH, pH decreases but remains greater than 7 . Reason (R) : Addition of overset(o+)NH_(4) ion decreases ionisation of NH_(4)OH , thus [overset(Theta)OH] decreases and also pH decreases.

Assertion :- In NH_(4)NO_(3) , the oxidation number of the two N-atoms is not equal. Reason :- One N atom is present in the ammonium ion while the other is present in the nitrate ion.

A: Number of ions in 9 gram of NH_(4)^(+) is equal to Avogadro's number ( N_(A) ). R: Number of ions is equal to number of atoms.

Assertion : The pH of NH_(4)Cl solution in water is less than 7 and pH of CH_(3)COONa solution is more than 7. Reason : NH_(4)Cl is a salt of weak NH_(4)OH and strong acid HCl whereas CH_(3)COONa is salt of a weak acid CH_(3)COOH and strong base NaOH.(a)If both assertion and reason are true and reason is the correct explanation of assertion. (b)If both assertion and reason are true but reason is not the correct explanation of assertion. (c)If assertion is true but reason is false. (d)If both assertion and reason are false

Assertion :- A solution of NH_(4)Cl in water is acidic in nature. Reacon : - Ammonium ions undergo hydroysis to from NH_(4)OH .

Lambda_((m)(NH_(4)OH))^(@) is equal to

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