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N(2)O(3) overset(R.T.) to NO+NO(2)...

`N_(2)O_(3) overset(R.T.) to NO+NO_(2)`

A

For disproportionation reaction.

B

For comproportionation reaction.

C

For either intermolecular redox reaction or displacement reaction

D

For either thermal combination redox reaction or thermal decomposition redox reaction.

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The correct Answer is:
To solve the given reaction \( N_2O_3 \) at room temperature producing \( NO + NO_2 \), we will analyze the oxidation states of nitrogen in the reactants and products to determine the type of reaction. ### Step-by-Step Solution: 1. **Identify the Reactants and Products**: The reactant is \( N_2O_3 \) and the products are \( NO \) (nitric oxide) and \( NO_2 \) (nitrogen dioxide). 2. **Determine the Oxidation States**: - In \( N_2O_3 \), the oxidation state of nitrogen can be calculated as follows: - Let the oxidation state of nitrogen be \( x \). - The formula for \( N_2O_3 \) gives: \( 2x + 3(-2) = 0 \) (since oxygen has an oxidation state of -2). - Solving this: \( 2x - 6 = 0 \) → \( 2x = 6 \) → \( x = +3 \). - Therefore, the oxidation state of nitrogen in \( N_2O_3 \) is +3. - In \( NO \), the oxidation state of nitrogen is +2. - In \( NO_2 \), the oxidation state of nitrogen is +4. 3. **Analyze Changes in Oxidation States**: - From \( N_2O_3 \) to \( NO \): - The oxidation state changes from +3 to +2 (reduction). - From \( N_2O_3 \) to \( NO_2 \): - The oxidation state changes from +3 to +4 (oxidation). 4. **Identify the Type of Reaction**: - Since one part of the reactant \( N_2O_3 \) is oxidized (to \( NO_2 \)) and another part is reduced (to \( NO \)), this is a classic example of a disproportionation reaction. - In a disproportionation reaction, a single reactant is both oxidized and reduced, resulting in two different products. 5. **Conclusion**: - The reaction \( N_2O_3 \) at room temperature producing \( NO + NO_2 \) is classified as a **disproportionation reaction**. ### Final Answer: The correct option for the type of reaction is **disproportionation reaction**. ---
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VK JAISWAL ENGLISH-TYPES OF REACTIONS-SUBJECTIVE PROBLEMS
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