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Select the compound in which HCl is not ...

Select the compound in which HCl is not the product of Hydrolysis:

A

`NCl_(3)`

B

`PCl_(3)`

C

`AsCl_(3)`

D

`BiCl_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question of which compound does not produce HCl upon hydrolysis, we will analyze the hydrolysis reactions of the given compounds step by step. ### Step 1: Analyze the first compound, NCl3 (Nitrogen trichloride) - When NCl3 reacts with water (H2O), the reaction is as follows: \[ \text{NCl}_3 + 3 \text{H}_2\text{O} \rightarrow \text{NH}_3 + 3 \text{HOCl} \] - In this reaction, we produce NH3 (ammonia) and HOCl (hypochlorous acid), but no HCl is formed. ### Step 2: Analyze the second compound, PCl3 (Phosphorus trichloride) - The hydrolysis of PCl3 can be written as: \[ \text{PCl}_3 + 3 \text{H}_2\text{O} \rightarrow \text{H}_3\text{PO}_3 + 3 \text{HCl} \] - Here, we produce H3PO3 (phosphorous acid) and 3 moles of HCl. ### Step 3: Analyze the third compound, AsCl3 (Arsenic trichloride) - The hydrolysis reaction for AsCl3 is: \[ \text{AsCl}_3 + 3 \text{H}_2\text{O} \rightarrow \text{H}_3\text{AsO}_3 + 3 \text{HCl} \] - This reaction also produces H3AsO3 (arsenic acid) and 3 moles of HCl. ### Step 4: Analyze the fourth compound, BiCl3 (Bismuth trichloride) - The hydrolysis of BiCl3 can be expressed as: \[ \text{BiCl}_3 + \text{H}_2\text{O} \rightarrow \text{BiOCl} + 2 \text{HCl} \] - In this case, we produce BiOCl (bismuth oxychloride) and 2 moles of HCl. ### Conclusion From the analysis of all four compounds, we can conclude that: - NCl3 does not produce HCl upon hydrolysis, while PCl3, AsCl3, and BiCl3 do produce HCl. Thus, the compound in which HCl is not the product of hydrolysis is **NCl3**.

To solve the question of which compound does not produce HCl upon hydrolysis, we will analyze the hydrolysis reactions of the given compounds step by step. ### Step 1: Analyze the first compound, NCl3 (Nitrogen trichloride) - When NCl3 reacts with water (H2O), the reaction is as follows: \[ \text{NCl}_3 + 3 \text{H}_2\text{O} \rightarrow \text{NH}_3 + 3 \text{HOCl} \] - In this reaction, we produce NH3 (ammonia) and HOCl (hypochlorous acid), but no HCl is formed. ...
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VK JAISWAL ENGLISH-TYPES OF REACTIONS-LEVEL 2
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