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I^(-)(aq.)+MnO(4)^(-)(aq.)overset(H^(+))...

`I^(-)(aq.)+MnO_(4)^(-)(aq.)overset(H^(+))toX+Mn^(2+)(aq.)`
`I^(-)(aq.)+MnO_(4)^(-)(aq.) underset("weakly "OH^(-))overset("Neutral or")to Y+MnO_(2)`
`MnO_(4)^(-)(aq.)+Mn^(2+)(aq.) overset(ZnSO_(4)) to Z+4H^(+)`
Product X, Y and Z are respectively.

A

`I_(2),IO_(3)^(-),MnO_(2)`

B

`IO_(3)^(-),I_(2),MnO_(2)`

C

`I_(2),IO_(3)^(-),MnO_(4)^(2-)`

D

`IO_(3)^(-),I_(2),MnO_(4)^(2-)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given question, we need to analyze the reactions step by step and identify the products X, Y, and Z based on the provided information. ### Step 1: Analyzing the first reaction The first reaction is: \[ I^{-} (aq) + MnO_{4}^{-} (aq) \overset{H^{+}}{\rightarrow} X + Mn^{2+} (aq) \] - In acidic medium, the permanganate ion (\(MnO_{4}^{-}\)) acts as a strong oxidizing agent. - The iodide ion (\(I^{-}\)) will be oxidized to iodine (\(I_{2}\)). - The \(MnO_{4}^{-}\) will be reduced to \(Mn^{2+}\). Thus, the product \(X\) is: \[ X = I_{2} \] ### Step 2: Analyzing the second reaction The second reaction is: \[ I^{-} (aq) + MnO_{4}^{-} (aq) \underset{\text{weakly } OH^{-}}{\rightarrow} Y + MnO_{2} \] - In a neutral or weakly basic medium, \(MnO_{4}^{-}\) is still an oxidizing agent, but it oxidizes iodide (\(I^{-}\)) to iodate (\(IO_{3}^{-}\)). - The \(MnO_{4}^{-}\) is reduced to manganese dioxide (\(MnO_{2}\)). Thus, the product \(Y\) is: \[ Y = IO_{3}^{-} \] ### Step 3: Analyzing the third reaction The third reaction is: \[ MnO_{4}^{-} (aq) + Mn^{2+} (aq) \overset{ZnSO_{4}}{\rightarrow} Z + 4H^{+} \] - This reaction involves the permanganate ion reacting with manganese in the +2 oxidation state. - This is a disproportionation reaction where \(MnO_{4}^{-}\) (Mn in +7 oxidation state) and \(Mn^{2+}\) (Mn in +2 oxidation state) yield manganese in the +4 oxidation state, which is \(MnO_{2}\). Thus, the product \(Z\) is: \[ Z = MnO_{2} \] ### Summary of Products - \(X = I_{2}\) - \(Y = IO_{3}^{-}\) - \(Z = MnO_{2}\) ### Final Answer The products \(X\), \(Y\), and \(Z\) are: - \(X = I_{2}\) - \(Y = IO_{3}^{-}\) - \(Z = MnO_{2}\)

To solve the given question, we need to analyze the reactions step by step and identify the products X, Y, and Z based on the provided information. ### Step 1: Analyzing the first reaction The first reaction is: \[ I^{-} (aq) + MnO_{4}^{-} (aq) \overset{H^{+}}{\rightarrow} X + Mn^{2+} (aq) \] - In acidic medium, the permanganate ion (\(MnO_{4}^{-}\)) acts as a strong oxidizing agent. - The iodide ion (\(I^{-}\)) will be oxidized to iodine (\(I_{2}\)). ...
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VK JAISWAL ENGLISH-TYPES OF REACTIONS-LEVEL 2
  1. In which of the following redox reaction precipitate is not formed?

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  2. Which metal sulphide is soluble in excess NH(3) solution?

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  3. I^(-)(aq.)+MnO(4)^(-)(aq.)overset(H^(+))toX+Mn^(2+)(aq.) I^(-)(aq.)+...

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  4. Br(2)+NaOH overset(R.T.) to Y+Z If Y gives precipitate with AgNO(3),...

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  5. (P)overset(Delta)to(Q)Metallic solid +(R)uarr+(S)uarr (X)overset(Del...

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  6. Iodine is not oxidized to iodic acid/iodicanhydride by:

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  7. Colourless gas that has oxidising as well as reducing properties:

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  8. Pb+Dil.HNO(3) overset(Warm)toP+Quarr+H(2)O Incorrect statement for Q...

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  9. Which reaction has positive value of DeltaG^(@)?

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  10. Which does not undergo comproportionation reaction?

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  11. Select the incorrect match:

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  12. Cu^(2+)(aq.)+X^(-)(aq.)overset(R.T.)toCuX darr+X(2) 'X' cannot be:

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  13. In which of the following reaction SO(2) gas is not produced?

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  14. Which metal gives NH(4)NO(3), when react with dilute HNO(3) acid?

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  15. Select the salt whose aqueous solution is not green:

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  16. Select the ion exchange reaction, which proceeds to forward direction ...

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  17. Which of the following metal hydroxide is not soluble in exces of NH(3...

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  18. Which of the following combination of reagents does not undergo redox ...

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  19. K(4)[Fe(CN)(6)]+M^(x+)(aq.)to underset("Coloured precipitate")(M(4)[Fe...

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  20. Sodium salt solution +AgNO(3)"soln."toColoured precipitate. If colou...

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