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Pb+Dil.HNO(3) overset(Warm)toP+Quarr+H(2...

`Pb+Dil.HNO_(3) overset(Warm)toP+Quarr+H_(2)O`
Incorrect statement for Q is:

A

Paramagnetic colourless gas

B

It is oxidized to paramagnetic coloured gas by air

C

It combines with `Fe_(2)(SO_(4))_(3)`

D

It is also obtained by disproportionation of `HNO_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction of lead (Pb) with dilute nitric acid (HNO3) and identify the incorrect statement about the product Q (which is nitric oxide, NO), we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reaction**: The reaction of lead (Pb) with dilute nitric acid (HNO3) when warmed can be represented as: \[ \text{Pb} + \text{Dil. HNO}_3 \xrightarrow{\text{Warm}} \text{Pb(NO}_3\text{)}_2 + \text{NO} + \text{H}_2\text{O} \] Here, P is Pb(NO3)2, and Q is NO. 2. **Analyze Product Q (NO)**: - NO (nitric oxide) is the product formed in this reaction. - It is important to check the properties of NO to determine the incorrect statement. 3. **Evaluate Statements**: - **Statement 1**: "NO is a paramagnetic colored gas." - NO is indeed paramagnetic because it has an unpaired electron. However, it is colorless, not colored. Therefore, this statement is partially incorrect. - **Statement 2**: "NO is oxidized to a paramagnetic colored gas by air." - This statement is correct. NO can be oxidized to NO2, which is a brown colored gas. - **Statement 3**: "NO combines with Fe2(SO4)3." - This statement is incorrect. NO does not react with Fe2(SO4)3 (ferric sulfate). It can react with FeSO4 (ferrous sulfate) but not with Fe2(SO4)3. - **Statement 4**: "NO can also be obtained by the disproportionation of HNO2." - This statement is correct. HNO2 can disproportionate to form NO and HNO3. 4. **Identify the Incorrect Statement**: - After analyzing all statements, the incorrect statement regarding Q (NO) is: - **Statement 3**: "NO combines with Fe2(SO4)3." ### Final Answer: The incorrect statement for Q (NO) is that it combines with Fe2(SO4)3. ---

To solve the question regarding the reaction of lead (Pb) with dilute nitric acid (HNO3) and identify the incorrect statement about the product Q (which is nitric oxide, NO), we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reaction**: The reaction of lead (Pb) with dilute nitric acid (HNO3) when warmed can be represented as: \[ \text{Pb} + \text{Dil. HNO}_3 \xrightarrow{\text{Warm}} \text{Pb(NO}_3\text{)}_2 + \text{NO} + \text{H}_2\text{O} ...
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VK JAISWAL ENGLISH-TYPES OF REACTIONS-LEVEL 2
  1. Iodine is not oxidized to iodic acid/iodicanhydride by:

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  2. Colourless gas that has oxidising as well as reducing properties:

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  3. Pb+Dil.HNO(3) overset(Warm)toP+Quarr+H(2)O Incorrect statement for Q...

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  4. Which reaction has positive value of DeltaG^(@)?

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  5. Which does not undergo comproportionation reaction?

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  6. Select the incorrect match:

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  7. Cu^(2+)(aq.)+X^(-)(aq.)overset(R.T.)toCuX darr+X(2) 'X' cannot be:

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  8. In which of the following reaction SO(2) gas is not produced?

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  9. Which metal gives NH(4)NO(3), when react with dilute HNO(3) acid?

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  10. Select the salt whose aqueous solution is not green:

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  11. Select the ion exchange reaction, which proceeds to forward direction ...

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  12. Which of the following metal hydroxide is not soluble in exces of NH(3...

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  13. Which of the following combination of reagents does not undergo redox ...

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  14. K(4)[Fe(CN)(6)]+M^(x+)(aq.)to underset("Coloured precipitate")(M(4)[Fe...

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  15. Sodium salt solution +AgNO(3)"soln."toColoured precipitate. If colou...

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  16. Chlorine gas is not produced by heating:

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  17. Which of the following anion does not prodcue prepitate with BaCl(2) s...

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  18. Which of the following compound is completely water soluble?

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  19. Which chemical reaction contains incorrect products?

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  20. Which of the following compound undergoes disproportionation in presen...

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