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HgCl2 is a covalent compound, sparingly ...

`HgCl_2` is a covalent compound, sparingly soluble in water, the solubility increase by the addition of chloride ions due to:

A

common ion effect

B

formation of complex `[HgCl_(4)]^(2-)`

C

weakening of Hg-Cl bonds

D

strong ion-dipole forces

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The correct Answer is:
To solve the question regarding the solubility of \( \text{HgCl}_2 \) in the presence of chloride ions, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the Compound**: - \( \text{HgCl}_2 \) (mercuric chloride) is a covalent compound that is sparingly soluble in water. This means that it does not dissolve well in water under normal conditions. 2. **Effect of Adding Chloride Ions**: - When chloride ions (\( \text{Cl}^- \)) are added to a solution containing \( \text{HgCl}_2 \), the solubility of \( \text{HgCl}_2 \) increases. 3. **Formation of a Complex Ion**: - The addition of chloride ions leads to the formation of a complex ion. Specifically, the reaction can be represented as: \[ \text{HgCl}_2 + 2\text{Cl}^- \rightarrow \text{HgCl}_4^{2-} \] - In this reaction, \( \text{HgCl}_2 \) reacts with two chloride ions to form the complex ion \( \text{HgCl}_4^{2-} \). 4. **Reason for Increased Solubility**: - The formation of the complex ion \( \text{HgCl}_4^{2-} \) effectively removes \( \text{HgCl}_2 \) from the solution as it shifts the equilibrium. This results in more \( \text{HgCl}_2 \) dissolving to maintain the equilibrium, thereby increasing the overall solubility of \( \text{HgCl}_2 \). 5. **Conclusion**: - The increase in solubility of \( \text{HgCl}_2 \) upon the addition of chloride ions is primarily due to the formation of the complex ion \( \text{HgCl}_4^{2-} \). ### Final Answer: The solubility of \( \text{HgCl}_2 \) increases with the addition of chloride ions due to the formation of the complex ion \( \text{HgCl}_4^{2-} \).
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