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Copper is very slowly oxidised on the su...

Copper is very slowly oxidised on the surface in moist air, giving a green coating of vergiris is :

A

`Cu_(2)O`

B

`CuCO_(3)`

C

`Cu(CH_(3)COO)_(2)*Cu(OH)_(2)`

D

`CuSO_(4)`

Text Solution

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The correct Answer is:
To solve the question regarding the oxidation of copper in moist air and the formation of a green coating known as verdigris, we can break down the process step by step. ### Step-by-Step Solution: 1. **Understanding the Environment**: - Copper is exposed to moist air, which contains both carbon dioxide (CO2) and oxygen (O2). 2. **Oxidation Reaction**: - In the presence of moisture and air, copper undergoes a slow oxidation process. The general reaction can be represented as: \[ \text{Cu} + \text{O}_2 + \text{H}_2\text{O} \rightarrow \text{Cu(OH)}_2 \] - Here, copper reacts with oxygen and water to form copper(II) hydroxide. 3. **Formation of Carbonate**: - The copper(II) hydroxide can further react with carbon dioxide in the air to form copper(II) carbonate: \[ \text{Cu(OH)}_2 + \text{CO}_2 \rightarrow \text{CuCO}_3 + \text{H}_2\text{O} \] 4. **Reaction with Acetic Acid**: - When copper(II) carbonate reacts with acetic acid (CH3COOH), it forms a complex that gives the characteristic green color of verdigris: \[ \text{CuCO}_3 + 2\text{CH}_3\text{COOH} \rightarrow \text{Cu(CH}_3\text{COO})_2 + \text{H}_2\text{O} + \text{CO}_2 \] 5. **Conclusion**: - The green coating observed on copper is indeed verdigris, which is primarily composed of copper(II) acetate and other copper compounds formed through these reactions. ### Final Answer: The green coating of verdigris on copper is formed as a result of its slow oxidation in moist air, leading to the formation of copper(II) hydroxide and subsequently copper(II) carbonate, which reacts with acetic acid.
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