Assertion: `CuSO_(4)*5H_(2)O and FeSO_(4)*7H_(2)O` are blue and green colour compounds respectively.
Reason: Both compounds have their specific colour due to phenomenon of polarisation of anion.

Options

A. If both assertion and reason are true and the reason is the correct explanation of assertion
B. If both assertion and reason are true and the reason is not the correct explanation of assertion
C. If assertion is false but reason is true
D. If assertion is true but the reason is false

Answer

To solve the question, we need to analyze the assertion and reason statements provided:

### Step 1: Analyze the Assertion
- The assertion states that `CuSO4·5H2O` (copper(II) sulfate pentahydrate) is a blue compound and `FeSO4·7H2O` (iron(II) sulfate heptahydrate) is a green compound.
- **Copper(II) sulfate** has a blue color due to the presence of unpaired electrons in its d-orbitals, which allows for d-d transitions.
- **Iron(II) sulfate** appears green due to its own electronic configuration, which also allows for d-d transitions with unpaired electrons.

### Conclusion for Step 1:
- The assertion is **true** because both compounds are indeed colored as stated.

### Step 2: Analyze the Reason
- The reason provided states that the specific colors of both compounds are due to the phenomenon of polarization of the anion.
- Polarization refers to the distortion of the electron cloud of an anion by a cation. However, the color of transition metal compounds is primarily due to the presence of unpaired electrons and the d-d transitions that occur, not due to polarization of the anion.

### Conclusion for Step 2:
- The reason is **false** because the color is not due to polarization but rather due to d-d transitions involving unpaired electrons.

### Final Conclusion:
- The assertion is true, but the reason is false. Therefore, the correct answer is that the assertion is true, but the reason is false.

### Summary of Steps:
1. **Assertion Analysis**: Confirmed that both `CuSO4·5H2O` and `FeSO4·7H2O` are colored due to unpaired electrons.
2. **Reason Analysis**: Determined that polarization of the anion does not explain the color of these compounds.