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Choose the correct order of C-C bond len...

Choose the correct order of C-C bond length in the given compounds:

A

Acetylene`lt`ethylene`lt`graphite`lt`benzene`lt`ethane

B

acetylene`lt`ethylene`lt`benzene`lt`graphite`lt`ethane

C

acetylene`lt`graphite`lt`ethylene`lt`benzene`lt`ethane

D

acetylene`lt`benzene`lt`graphite`lt`entylene`lt`ethane

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The correct Answer is:
To determine the correct order of C-C bond lengths in the given compounds, we need to analyze the types of bonds present in each compound. The compounds we are considering are acetylene, ethylene, graphite, benzene, and ethane. ### Step-by-Step Solution: 1. **Identify the Compounds and Their Bond Types**: - **Acetylene (C2H2)**: Contains a triple bond (C≡C). - **Ethylene (C2H4)**: Contains a double bond (C=C). - **Graphite**: Consists of sp² hybridized carbon atoms bonded in sheets, primarily involving single bonds (C-C) with some delocalized π-bonds. - **Benzene (C6H6)**: Contains sp² hybridized carbon atoms with delocalized π-bonds, giving it a resonance structure but primarily single bond character. - **Ethane (C2H6)**: Contains a single bond (C-C). 2. **Understanding Bond Lengths**: - Single bonds (C-C) are the longest. - Double bonds (C=C) are shorter than single bonds. - Triple bonds (C≡C) are the shortest. - In graphite and benzene, while they have some double bond character due to resonance, they are primarily considered as single bonds. 3. **Rank the Compounds by Bond Length**: - **Longest Bond Length**: Ethane (C-C single bond) > Graphite (C-C single bond with some delocalization) > Benzene (C-C with partial double bond character) > Ethylene (C=C double bond) > Acetylene (C≡C triple bond). - Therefore, the order from longest to shortest bond length is: - Ethane > Graphite > Benzene > Ethylene > Acetylene. 4. **Conclusion**: - The correct order of C-C bond lengths in the given compounds is: - **Ethane > Graphite > Benzene > Ethylene > Acetylene**. ### Final Answer: The correct order of C-C bond lengths is: **Ethane > Graphite > Benzene > Ethylene > Acetylene**.
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