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Two oxides of Nitrogen, NO and NO(2) rea...

Two oxides of Nitrogen, NO and `NO_(2)` reacts together at 253 K and form a compound Nitrogen X.X reacts with water to yield another compound of Nitrogen Y. The shape of the anion of Y molecule is

A

triangular planar

B

triangular pyramidal

C

tetrahedron

D

square planar

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The correct Answer is:
To solve the problem step by step, we will analyze the reactions and compounds formed: ### Step 1: Identify the Reaction Between NO and NO2 The two oxides of nitrogen, NO (nitric oxide) and NO2 (nitrogen dioxide), react together at 253 K. The reaction can be represented as follows: \[ 2 \text{NO} + \text{NO}_2 \rightarrow \text{N}_2\text{O}_3 \] ### Step 2: Identify Compound X From the reaction above, we can see that the product formed is \( \text{N}_2\text{O}_3 \). Thus, the compound X is: \[ \text{X} = \text{N}_2\text{O}_3 \] ### Step 3: Reaction of Compound X with Water Next, we need to determine what happens when \( \text{N}_2\text{O}_3 \) reacts with water. The reaction can be represented as: \[ \text{N}_2\text{O}_3 + \text{H}_2\text{O} \rightarrow 2 \text{HNO}_2 \] Here, \( \text{HNO}_2 \) is nitrous acid, which is the compound Y. ### Step 4: Identify the Structure of Compound Y The structure of nitrous acid \( \text{HNO}_2 \) can be drawn as follows: - Nitrogen (N) is bonded to one hydroxyl group (–OH) and has a double bond with one oxygen (O). - The remaining oxygen carries a negative charge. The structural formula can be represented as: \[ \text{HNO}_2: \quad \text{O} \quad \text{N} \quad \text{O}^- \] ### Step 5: Determine the Shape of the Anion of Y The anion of \( \text{HNO}_2 \) is \( \text{NO}_2^- \). To determine its shape, we need to consider the hybridization and geometry: - The nitrogen atom in \( \text{NO}_2^- \) has one lone pair and forms two bonds (one double bond with one oxygen and one single bond with another oxygen). - The hybridization of nitrogen in this case is \( \text{sp}^2 \) because it has three regions of electron density (two bonds and one lone pair). ### Step 6: Conclusion on the Shape The geometry of \( \text{NO}_2^- \) is trigonal planar due to the \( \text{sp}^2 \) hybridization, which means the shape of the anion is planar. ### Final Answer The shape of the anion of Y (which is \( \text{NO}_2^- \)) is trigonal planar. ---

To solve the problem step by step, we will analyze the reactions and compounds formed: ### Step 1: Identify the Reaction Between NO and NO2 The two oxides of nitrogen, NO (nitric oxide) and NO2 (nitrogen dioxide), react together at 253 K. The reaction can be represented as follows: \[ 2 \text{NO} + \text{NO}_2 \rightarrow \text{N}_2\text{O}_3 \] ...
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VK JAISWAL ENGLISH-p-BLOCK ELEMENTS-LEVEL 2
  1. The correct code for stability, of oxidation states for given cations ...

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  2. Nitrogen gas is liberated by thermal decomposition of:

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  3. Two oxides of Nitrogen, NO and NO(2) reacts together at 253 K and form...

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  4. Consider the following sequence of reaction: Na+NH(3)(g) to [X]overs...

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  5. Which of the following oxyacid contains both P-H and P-P bond simultan...

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  6. Among the following statement which one is true?

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  7. Which of the following statements regarding N(2)O(4) is not correct?

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  8. Which of the following on heating produces NO(2) ?

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  9. Which of the following equation is incorrectly written?

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  10. The cyclotrimetaphosphoric acid is:

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  11. A+H(2)O to B+HCl B+H(2)O to C+HCl Compound (A), (B) and (C) will b...

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  12. It is recommended that ammonia bottles be opened after cooling in ice ...

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  13. Which of the following statements are correct about the reaction betwe...

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  14. In which of the following acids, P-P bonds is present?

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  15. NH(3)+O(2) underset(Delta)overset(Pt) to A+H(2)O A+O(2) to B, B+O(...

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  16. The formation of PH(4)^(+) is diffficult compaired to NH(4)^(+) becaus...

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  17. Nitrozen (i) oxide is produced by

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  18. Amongst the following compounds (I) H(5)P(3)O(10) (II) H(6)P(4)O(1...

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  19. Match List-I with List-II and select the correct answer using the code...

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  20. Which is the correct sequence in the following properties. For the cor...

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