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Predict the correct product when Cl(2) p...

Predict the correct product when `Cl_(2)` passed through `H-overset(18)(O)-overset(18)(O)-H` solution.

A

`H^(+)+Cl^(-)+O_(2)` (both oxygen having 18)

B

HOCl and `HClO_(2)` (all oxygen having 18)

C

`HClO_(4)` and HCl (all oxygen having 18)

D

`Cl_(2)O and H_(2)O` (all oxygen having 18)

Text Solution

AI Generated Solution

The correct Answer is:
To predict the correct product when \( Cl_2 \) is passed through \( H_2^{18}O \) solution, we can follow these steps: ### Step 1: Identify the Reactants We have chlorine gas (\( Cl_2 \)) and hydrogen peroxide (\( H_2O_2 \)), where the oxygen atoms are specifically labeled as \( ^{18}O \). ### Step 2: Understand the Reaction When chlorine gas reacts with hydrogen peroxide, the general reaction can be represented as: \[ Cl_2 + H_2O_2 \rightarrow HCl + O_2 \] In this reaction, chlorine reacts with hydrogen peroxide to produce hydrochloric acid (HCl) and oxygen gas (O2). ### Step 3: Consider the Isotopes Since we are using \( H_2^{18}O \), the oxygen in the products will also contain the \( ^{18}O \) isotope. Therefore, when \( H_2O_2 \) decomposes in the presence of \( Cl_2 \), the oxygen produced will also be \( ^{18}O \). ### Step 4: Write the Products From the reaction, we can deduce that: - The products will include \( HCl \) (which consists of \( H^+ \) and \( Cl^- \)) and \( O_2 \) (which will consist of \( O^{18} \) due to the initial reactants). ### Step 5: Finalize the Reaction Thus, the complete balanced reaction can be summarized as: \[ Cl_2 + H_2^{18}O_2 \rightarrow 2 HCl + O_2^{18} \] However, since we are interested in the products, we can simplify it to: \[ H^+ + Cl^- + O_2^{18} \] ### Conclusion The correct product when \( Cl_2 \) is passed through \( H_2^{18}O \) solution is: \[ H^+ + Cl^- + O_2^{18} \]
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