Home
Class 12
CHEMISTRY
Xenon tetrafluoride, XeF(4) is:...

Xenon tetrafluoride, `XeF_(4)` is:

A

tetrahedral annd acts as a fluoride donor with `SbF_(5)`

B

square planar and acts as a fluoride donor with `PF_(5)`

C

square planar and acts as fluoride donor with `NaF`

D

see-saw shape and acts as a fluoride donor with `AsF_(5)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the nature of xenon tetrafluoride, \( \text{XeF}_4 \), we will analyze its structure and reactivity step by step. ### Step 1: Determine the molecular geometry of \( \text{XeF}_4 \) 1. **Valence Electrons Calculation**: - Xenon (Xe) has 8 valence electrons. - Each fluorine (F) has 7 valence electrons, and there are 4 fluorine atoms. - Total valence electrons = \( 8 + (4 \times 7) = 8 + 28 = 36 \) electrons. 2. **Lewis Structure**: - Place xenon in the center and surround it with 4 fluorine atoms. - Each fluorine atom forms a single bond with xenon, using 8 electrons (4 bonds). - This leaves us with \( 36 - 8 = 28 \) electrons. - Distribute the remaining electrons as lone pairs. Xenon will have 2 lone pairs. 3. **Geometry**: - The presence of 4 bonded pairs (from F) and 2 lone pairs around the xenon atom leads to a square planar geometry. - The 4 fluorine atoms occupy the corners of a square, while the 2 lone pairs are positioned opposite each other. ### Step 2: Analyze the options - **Tetrahedral**: Incorrect, as the geometry is square planar. - **Square Planar**: Correct, as derived from the Lewis structure. - **Seesaw Shape**: Incorrect, as this shape corresponds to a different arrangement of lone pairs and bonded pairs. ### Step 3: Reactivity with \( \text{PF}_5 \) 1. **Reaction Analysis**: - When \( \text{XeF}_4 \) reacts with \( \text{PF}_5 \), it forms \( \text{XeF}_3^+ \) and \( \text{PF}_6^- \). - This indicates that \( \text{XeF}_4 \) donates a fluoride ion to \( \text{PF}_5 \). 2. **Conclusion**: - Since \( \text{XeF}_4 \) acts as a fluoride donor, it confirms that it can participate in reactions as a Lewis acid. ### Final Answer Xenon tetrafluoride, \( \text{XeF}_4 \), is **square planar** and acts as a fluoride donor in reactions. ---
Promotional Banner

Topper's Solved these Questions

  • p-BLOCK ELEMENTS

    VK JAISWAL ENGLISH|Exercise LEVEL 3 (PASSAGE TYPE)|17 Videos
  • p-BLOCK ELEMENTS

    VK JAISWAL ENGLISH|Exercise ONE OR MORE ANSWERS IS/ARE CORRECT|95 Videos
  • p-BLOCK ELEMENTS

    VK JAISWAL ENGLISH|Exercise SUBJECTIVE PROBLEMS|35 Videos
  • METALLURGY

    VK JAISWAL ENGLISH|Exercise ASSERTION-REASON TYPE QUESTIONS|29 Videos
  • PERIODIC PROPERTIES

    VK JAISWAL ENGLISH|Exercise MATCH THE COLUMN|11 Videos

Similar Questions

Explore conceptually related problems

Xenon difluoride is

Xenon tetrafluoride has hybridisation and structure as

How are xenon fluorides XeF_(2) , XeF_(4) and XeF_(6) obtained?

Draw the structure of xenon tetrafluoride molecule. State the hybridisation of the central atom and the geometry of the molecule.

Draw the structure of xenon hexaluoride (XeF_6) molecule and state the hybridisation of the central atom.

Give reasons : (i)Xenon does not form fluorides such as XeF_(3) and XeF_(5) .(ii)Out of noble gases, only xenon is known to form established chemicals compounds.

Assertion : XeF_(4) is square planar Reason :Xe atom in XeF_(4) is dsp^(2) hybridised

If number of lone pairs on central atom in XeF_(2), XeF_(4) and XeF_(6) are x, y, z. What is the sum of x+y+z here?

The structure of the noble gas compound XeF_(4) is :

The structure of the noble gas compound XeF_(4) is :

VK JAISWAL ENGLISH-p-BLOCK ELEMENTS-LEVEL 2
  1. The incorrect order is:

    Text Solution

    |

  2. The correct statement regarding perxenate ion (XeO(6)^(4-)) is:

    Text Solution

    |

  3. XeF(2) and XeF(6) are separately hydrolysed then:

    Text Solution

    |

  4. Mf + XeF(4) rarr M^(+) A^(-) (M^(+)- alkali metal cation) The state of...

    Text Solution

    |

  5. Xenon tetrafluoride, XeF(4) is:

    Text Solution

    |

  6. XeF(6) dissolves in anhydrous HF to give a good conducting solution wh...

    Text Solution

    |

  7. Which of the following is not true about helium ?

    Text Solution

    |

  8. SbF(5) reacts with XeF(4) to form an adduct. The shapes of cation and ...

    Text Solution

    |

  9. Consider the followingg transformations: (I) XeF(6)+NaF to Na^(+)[Xe...

    Text Solution

    |

  10. Which of the following is an uncommon hydrolysis product of XeF(2) and...

    Text Solution

    |

  11. Incorrect statement regarding following reaction is:

    Text Solution

    |

  12. Which of the following noble gases does not form clatherates?

    Text Solution

    |

  13. Correct order of bond angle in given species is:

    Text Solution

    |

  14. The incorrect order is:

    Text Solution

    |

  15. Among the following, cyclic species are: (I) H(5)P(3)O(10) (II) [B...

    Text Solution

    |

  16. The substance that has the lowest boililng point is:

    Text Solution

    |

  17. Which of the following molecule can show Lewis acidity? (I) CO(2) ...

    Text Solution

    |

  18. Molecule having non-pola as well as polar bonds but the molecule as a ...

    Text Solution

    |

  19. Which of the following order is incorrect?

    Text Solution

    |

  20. Which of the following does not undergo Lewis acid-basic reaction?

    Text Solution

    |