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The incorrect order is:...

The incorrect order is:

A

`N gt P gt As`: strength of `pi`-bond with oxygen atom

B

`SiF_(4) gt SiCl_(4) gt SiBr_(4) gt SiI_(4)`: Thermal stability

C

`H_(2)S gt H_(2)Se gt H_(2)Te`: Arrhenious acid character

D

`CaBr_(2) gt MgBr_(2) gt BeBr_(2)` Melting point

Text Solution

AI Generated Solution

The correct Answer is:
To determine the incorrect order from the given options, we will analyze each statement step by step. ### Step 1: Analyze the first option **Statement:** Nitrogen > Phosphorus > Arsenic (in terms of strength of pi bond with oxygen) - **Explanation:** Nitrogen forms strong pπ-pπ bonds with oxygen due to its small size and effective orbital overlap. As we move down the group from nitrogen to phosphorus to arsenic, the size of the atoms increases, leading to poorer overlap and weaker bonds. Therefore, this order is correct. **Hint:** Consider the size and bonding characteristics of the elements involved. ### Step 2: Analyze the second option **Statement:** SiF4 > SiCl4 > SiBr4 > SiI4 (in terms of thermal stability) - **Explanation:** The thermal stability of these compounds is influenced by lattice enthalpy. The lattice enthalpy decreases as the size of the halide increases (F < Cl < Br < I). Since the charges (Q1 and Q2) remain constant, an increase in the size of the anion (R2) leads to a decrease in lattice enthalpy, making this order correct. **Hint:** Remember that lattice enthalpy is affected by the size of ions involved. ### Step 3: Analyze the third option **Statement:** H2S > H2Te (in terms of Arrhenius acid character) - **Explanation:** As we move down the group from H2S to H2Te, the bond length increases, resulting in weaker H-X bonds (where X is S or Te). This means that H2Te is a stronger acid than H2S due to its lower bond dissociation enthalpy. Therefore, the order H2S > H2Te is incorrect. **Hint:** Consider how bond length and strength affect acid character. ### Step 4: Analyze the fourth option **Statement:** CaBr2 > MgBr2 > BaBr2 (in terms of melting point) - **Explanation:** The melting point generally increases down the group in the alkaline earth metals due to increasing ionic size and stronger metallic bonding. Thus, this order is correct. **Hint:** Think about how melting points change with increasing atomic size in a group. ### Conclusion After analyzing all the options, we find that the incorrect order is: **H2S > H2Te** (Option 3)

To determine the incorrect order from the given options, we will analyze each statement step by step. ### Step 1: Analyze the first option **Statement:** Nitrogen > Phosphorus > Arsenic (in terms of strength of pi bond with oxygen) - **Explanation:** Nitrogen forms strong pπ-pπ bonds with oxygen due to its small size and effective orbital overlap. As we move down the group from nitrogen to phosphorus to arsenic, the size of the atoms increases, leading to poorer overlap and weaker bonds. Therefore, this order is correct. **Hint:** Consider the size and bonding characteristics of the elements involved. ...
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VK JAISWAL ENGLISH-p-BLOCK ELEMENTS-LEVEL 2
  1. The incorrect order is:

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  2. The correct statement regarding perxenate ion (XeO(6)^(4-)) is:

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  3. XeF(2) and XeF(6) are separately hydrolysed then:

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  4. Mf + XeF(4) rarr M^(+) A^(-) (M^(+)- alkali metal cation) The state of...

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  5. Xenon tetrafluoride, XeF(4) is:

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  6. XeF(6) dissolves in anhydrous HF to give a good conducting solution wh...

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  7. Which of the following is not true about helium ?

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  8. SbF(5) reacts with XeF(4) to form an adduct. The shapes of cation and ...

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  9. Consider the followingg transformations: (I) XeF(6)+NaF to Na^(+)[Xe...

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  10. Which of the following is an uncommon hydrolysis product of XeF(2) and...

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  11. Incorrect statement regarding following reaction is:

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  12. Which of the following noble gases does not form clatherates?

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  13. Correct order of bond angle in given species is:

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  14. The incorrect order is:

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  15. Among the following, cyclic species are: (I) H(5)P(3)O(10) (II) [B...

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  16. The substance that has the lowest boililng point is:

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  17. Which of the following molecule can show Lewis acidity? (I) CO(2) ...

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  18. Molecule having non-pola as well as polar bonds but the molecule as a ...

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  19. Which of the following order is incorrect?

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  20. Which of the following does not undergo Lewis acid-basic reaction?

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