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The following flow diagram represent the...

The following flow diagram represent the industrial preparation of nitric acid from ammonia:
`NH_(3)+underset(("excess air"))(O_(2)) underset(900^(@)C)overset((X))NO underset(air)overset((Y))to(Z)overset("water")toHNO_(3)+NO`
Q. Which line of entry describes the undefined reagents, products and reaction conditions?

A

X-Pt, Y-cool`(-25^(@)C)`, Z-`NO_(2)`

B

X-Ni, Y-cool `(-25^(@)C)`, Z-`N_(2)O`

C

X-Fe, Y-cool `(-11^(@)C)`, Z-`NO_(2)`

D

X-Pd, Y-high pressure, Z-`N_(2)O_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the undefined reagents, products, and reaction conditions in the flow diagram for the industrial preparation of nitric acid from ammonia, we can break down the process step by step. ### Step-by-Step Solution: 1. **Identify the Reactants**: - The first step in the reaction involves ammonia (NH₃) reacting with excess oxygen (O₂) from the air. - **Hint**: Look for the primary reactants in the flow diagram. 2. **Determine the Reaction Conditions**: - The reaction occurs at a temperature of 900°C. - **Hint**: Check the temperature conditions specified in the flow diagram. 3. **Identify the Catalyst**: - The process uses platinum as a catalyst (denoted as X in the flow diagram). - **Hint**: Catalysts are often indicated in chemical processes and can be found in the reaction conditions. 4. **Identify the First Product**: - The initial product formed from the reaction of NH₃ and O₂ is nitric oxide (NO). - **Hint**: Look for the product that is formed immediately after the reactants. 5. **Further Reactions**: - The nitric oxide (NO) is then oxidized in the presence of air (excess O₂) at lower temperatures (around -25°C) to form nitrogen dioxide (NO₂). - **Hint**: Pay attention to the subsequent reactions that follow the initial product. 6. **Final Products**: - The nitrogen dioxide (NO₂) undergoes hydrolysis to produce nitric acid (HNO₃) and regenerate some nitric oxide (NO). - **Hint**: Identify the final products of the reaction sequence. 7. **Summarize the Flow Diagram**: - The flow diagram can be summarized as follows: - **Reactants**: NH₃ + O₂ (excess air) - **Catalyst**: Platinum (X) - **Conditions**: 900°C for the first reaction and -25°C for the second reaction (Y) - **Intermediate Product**: NO (first product) - **Final Product**: HNO₃ + NO (after hydrolysis) ### Conclusion: Based on the breakdown, the undefined reagents, products, and reaction conditions in the flow diagram are: - **X**: Platinum (catalyst) - **Y**: Low temperature (-25°C) - **Z**: Nitrogen dioxide (NO₂) ### Final Answer: The line of entry that describes the undefined reagents, products, and reaction conditions is: - X = Platinum (catalyst) - Y = Low temperature (-25°C) - Z = Nitrogen dioxide (NO₂)
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