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Choose the correct statement regarding P...

Choose the correct statement regarding `PCl_(5)`

A

In solid phase, hybridisation of P-atom in cation is `sp^(3)`

B

In vapour phase, al P-Cl bond lengths are equal

C

In vapour and solid phase, central atom has no lone pair

D

In solid phase, anion has only one type of bond angle

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The correct Answer is:
A, C

In gaseous or vapour phase `PCl_(5)` exists as discrete molecule.

whereas in solid state it exists as `[PCl_(4)]^(+)[PCl_(6)]^(-)`
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