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Assertion: NaBO(3) //OH^(-) can be used ...

Assertion: `NaBO_(3) //OH^(-)` can be used for oxidation of `Cr^(3+)` to `Cr^(6+)`
Reason: IN alkaline medium `NaBO_(3)` produces `H_(2)O_(2)`

A

If both (A) and (R) are true and (R) is the correct explanation of (A)

B

if both (A) and (R) are true but (R) is not correct explanation of (A)

C

If (A) is true but (R) is false

D

If (A) is false but (R) is false

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the assertion and reason provided, we will analyze both statements step by step. ### Step 1: Understanding the Assertion The assertion states that `NaBO3 // OH^(-)` can be used for the oxidation of `Cr^(3+)` to `Cr^(6+)`. **Explanation:** - `NaBO3` is sodium perborate, which is known for its oxidizing properties. - In the presence of hydroxide ions (OH^-), sodium perborate can facilitate the oxidation of chromium ions. ### Step 2: Understanding the Reason The reason given is that in alkaline medium, `NaBO3` produces `H2O2` (hydrogen peroxide). **Explanation:** - In alkaline conditions, sodium perborate decomposes to produce hydrogen peroxide, which is a strong oxidizing agent. - The reaction can be summarized as: \[ \text{NaBO}_3 + \text{OH}^- \rightarrow \text{H}_2\text{O}_2 + \text{other products} \] ### Step 3: The Oxidation Reaction Now, we need to understand how `H2O2` can oxidize `Cr^(3+)` to `Cr^(6+)`. **Explanation:** - The oxidation of `Cr^(3+)` to `Cr^(6+)` can be represented as: \[ \text{Cr}^{3+} + \text{H}_2\text{O}_2 \rightarrow \text{CrO}_4^{2-} + \text{H}_2\text{O} \] - Here, `CrO4^(2-)` indicates that chromium is in the +6 oxidation state. ### Step 4: Conclusion Both the assertion and the reason are correct. The assertion is true because `NaBO3` can indeed oxidize `Cr^(3+)` to `Cr^(6+)`, and the reason is also true as `NaBO3` produces `H2O2` in alkaline medium, which is responsible for the oxidation. ### Final Answer - **Assertion:** True - **Reason:** True - **Conclusion:** The reason is the correct explanation of the assertion.
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