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Assertion: Aluminium and zinc metal evol...

Assertion: Aluminium and zinc metal evolve `H_(2)` gas from NaOH solution
Reason: Several non-metals such as P,S,Cl, etc. yield a hydride instead of `H_(2)` gas from NaOH

A

If both (A) and (R) are true and (R) is the correct explanation of (A)

B

if both (A) and (R) are true but (R) is not correct explanation of (A)

C

If (A) is true but (R) is false

D

If (A) is false but (R) is false

Text Solution

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The correct Answer is:
To solve the assertion-reason question, let's break it down step by step. ### Step 1: Analyze the Assertion The assertion states that "Aluminium and zinc metal evolve H₂ gas from NaOH solution." **Explanation:** - Both aluminum (Al) and zinc (Zn) are amphoteric metals. This means they can react with both acids and bases. - When aluminum reacts with sodium hydroxide (NaOH), it forms sodium aluminate and releases hydrogen gas: \[ 2 \text{Al} + 2 \text{NaOH} + 6 \text{H}_2\text{O} \rightarrow 2 \text{NaAl(OH)}_4 + 3 \text{H}_2 \uparrow \] - Similarly, zinc reacts with NaOH to form sodium zincate and also releases hydrogen gas: \[ \text{Zn} + 2 \text{NaOH} \rightarrow \text{Na}_2\text{Zn(OH)}_4 + \text{H}_2 \uparrow \] - Therefore, the assertion is **true**. ### Step 2: Analyze the Reason The reason states that "Several non-metals such as P, S, Cl, etc. yield a hydride instead of H₂ gas from NaOH." **Explanation:** - Non-metals like phosphorus (P), sulfur (S), and chlorine (Cl) do not produce hydrogen gas when reacting with NaOH. - For example: - Phosphorus reacts with NaOH to form sodium hypophosphite and phosphine gas: \[ \text{P} + 3 \text{NaOH} + 3 \text{H}_2\text{O} \rightarrow \text{NaH}_2\text{PO}_2 + \text{PH}_3 \uparrow \] - Sulfur reacts with NaOH to form sodium thiosulfate and other products: \[ 4 \text{S} + 6 \text{NaOH} \rightarrow \text{Na}_2\text{S}_2\text{O}_3 + \text{Na}_2\text{S} + 3 \text{H}_2\text{O} \] - Chlorine reacts with NaOH to produce sodium hypochlorite and other products: \[ \text{Cl}_2 + 2 \text{NaOH} \rightarrow \text{NaCl} + \text{NaClO} + \text{H}_2\text{O} \] - Therefore, the reason is also **true**. ### Step 3: Determine the Relationship Now we need to determine if the reason is the correct explanation of the assertion. - The assertion is about metals (Al and Zn) evolving hydrogen gas from NaOH. - The reason discusses non-metals yielding hydrides instead of hydrogen gas from NaOH. - There is no direct connection between the two statements; the behavior of metals does not explain the behavior of non-metals. ### Conclusion Both the assertion and the reason are true, but the reason is not the correct explanation of the assertion. **Final Answer: Option B** - Both assertion and reason are true, but reason is not the correct explanation of assertion. ---

To solve the assertion-reason question, let's break it down step by step. ### Step 1: Analyze the Assertion The assertion states that "Aluminium and zinc metal evolve H₂ gas from NaOH solution." **Explanation:** - Both aluminum (Al) and zinc (Zn) are amphoteric metals. This means they can react with both acids and bases. - When aluminum reacts with sodium hydroxide (NaOH), it forms sodium aluminate and releases hydrogen gas: ...
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