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Consider the following orders: (1) H(2...

Consider the following orders:
(1) `H_(2)SO_(4) gt H_(2)SO_(3):`boiling point
(2) `H_(2)O gt HF:` Extent of H-bond
(3) `H_(2)O lt H_(2)O_(2)`: Strength off H-bond.

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The correct Answer is:
To analyze the given orders, we will evaluate each statement step by step. ### Step 1: Analyzing the boiling point of H₂SO₄ and H₂SO₃ 1. **Molecular Formula of H₂SO₄**: Contains 2 Hydrogen (H), 1 Sulfur (S), and 4 Oxygen (O) atoms. 2. **Molecular Formula of H₂SO₃**: Contains 2 Hydrogen (H), 1 Sulfur (S), and 3 Oxygen (O) atoms. 3. **Molar Mass Calculation**: - Molar mass of H₂SO₄ = (2 × 1) + (1 × 32) + (4 × 16) = 98 g/mol - Molar mass of H₂SO₃ = (2 × 1) + (1 × 32) + (3 × 16) = 82 g/mol 4. **Conclusion**: Since H₂SO₄ has a greater molar mass than H₂SO₃, it has a higher boiling point. Thus, the order is: - **H₂SO₄ > H₂SO₃** (True) ### Step 2: Analyzing the extent of hydrogen bonding in H₂O and HF 1. **Hydrogen Bonding in H₂O**: - Water (H₂O) has two hydrogen atoms that can form hydrogen bonds with other water molecules. - Each water molecule can form up to 4 hydrogen bonds (2 from H and 2 lone pairs on O). 2. **Hydrogen Bonding in HF**: - HF has one hydrogen atom that can form a hydrogen bond with another HF molecule. - Each HF molecule can form only 1 hydrogen bond. 3. **Conclusion**: Since water can form more hydrogen bonds than HF, the extent of hydrogen bonding is: - **H₂O > HF** (True) ### Step 3: Analyzing the strength of hydrogen bonds in H₂O and H₂O₂ 1. **Hydrogen Bonding in H₂O**: - Water has a bent structure with a significant partial negative charge on oxygen and partial positive charges on hydrogens. - This leads to strong hydrogen bonding due to the high electronegativity of oxygen. 2. **Hydrogen Bonding in H₂O₂**: - Hydrogen peroxide (H₂O₂) has a different structure, where the hydrogen bonds are influenced by the presence of an additional oxygen atom. - The presence of two -OH groups in H₂O₂ results in weaker hydrogen bonds compared to H₂O. 3. **Conclusion**: The strength of hydrogen bonds in water is greater than in hydrogen peroxide: - **H₂O > H₂O₂** (False) ### Final Conclusion - The correct orders are: 1. **H₂SO₄ > H₂SO₃** (True) 2. **H₂O > HF** (True) 3. **H₂O < H₂O₂** (False) Thus, the correct statements are the first two, while the third statement is incorrect.
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