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2Cu^(2+)+5I^(-) to 2CuI darr+[X] [X]+2...

`2Cu^(2+)+5I^(-) to 2CuI darr+[X]`
`[X]+2S_(2)O_(3)^(2-) to 3[Y]+S_(4)O_(6)^(2-),X and Y` are:

A

`I_(3)^(-) and I^(-)`

B

`I_(2) and I_(3)^-`

C

`I_(2) and I^(-)`

D

`I_(3)^(-) and I_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, we need to analyze the given chemical equations and identify the unknown compounds X and Y. ### Step 1: Analyze the first reaction The first reaction is: \[ 2Cu^{2+} + 5I^{-} \rightarrow 2CuI + [X] \] In this reaction, copper ions (\(Cu^{2+}\)) react with iodide ions (\(I^{-}\)) to form copper iodide (\(CuI\)) and an unknown compound [X]. ### Step 2: Determine the unknown compound X To find [X], we need to balance the reaction. - On the left side, we have: - 2 copper ions (\(Cu^{2+}\)) contribute a total charge of +4. - 5 iodide ions (\(I^{-}\)) contribute a total charge of -5. - The total charge on the left is \(+4 - 5 = -1\). - On the right side, we have: - 2 \(CuI\) contributes 2 copper and 2 iodide ions, which gives a total charge of 0 (since \(CuI\) is neutral). - Therefore, to balance the charges, we need to account for the charge of [X]. The only way to balance the charges is if [X] is the triiodide ion (\(I_3^{-}\)), which has a charge of -1. Thus, we can write: \[ 2Cu^{2+} + 5I^{-} \rightarrow 2CuI + I_3^{-} \] So, we conclude that: \[ X = I_3^{-} \] ### Step 3: Analyze the second reaction The second reaction is: \[ [X] + 2S_2O_3^{2-} \rightarrow 3[Y] + S_4O_6^{2-} \] Substituting [X] with \(I_3^{-}\): \[ I_3^{-} + 2S_2O_3^{2-} \rightarrow 3[Y] + S_4O_6^{2-} \] ### Step 4: Determine the unknown compound Y In this reaction, we need to determine what [Y] is. - The triiodide ion (\(I_3^{-}\)) can react with thiosulfate ions (\(S_2O_3^{2-}\)) to produce iodide ions (\(I^{-}\)) and tetrathionate ions (\(S_4O_6^{2-}\)). - The balanced reaction would be: \[ I_3^{-} + 2S_2O_3^{2-} \rightarrow 3I^{-} + S_4O_6^{2-} \] Thus, we conclude that: \[ Y = I^{-} \] ### Final Answer The values of X and Y are: - \(X = I_3^{-}\) (triiodide ion) - \(Y = I^{-}\) (iodide ion)
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