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Consider the following sequence of tests...

Consider the following sequence of tests,
`M^(n+) overset(HCl)to ` white precipitate`overset(Delta)to` water soluble.
The metal ion `(M^(n+))` would be:

A

`Hg^(2+)`

B

`Ag^(+)`

C

`Pb^(2+)`

D

`Sn^(2+)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the metal ion \( M^{n+} \) based on the given sequence of tests, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the Tests**: The sequence of tests indicates that when \( M^{n+} \) is treated with dilute HCl, a white precipitate is formed. This suggests that \( M^{n+} \) could be one of the cations that form insoluble chlorides. 2. **Identifying Possible Cations**: The common cations that form white precipitates with dilute HCl are: - Silver ion \( \text{Ag}^+ \) - Lead ion \( \text{Pb}^{2+} \) - Mercury(I) ion \( \text{Hg}_2^{2+} \) 3. **Analyzing the Precipitate**: The white precipitate formed is likely a chloride salt. The precipitate must also be analyzed based on the next step, which indicates that upon heating, the white precipitate becomes water soluble. 4. **Testing Solubility Upon Heating**: - **Lead(II) chloride \( \text{PbCl}_2 \)**: This salt is known to be insoluble in cold water but becomes soluble when heated. - **Silver chloride \( \text{AgCl} \)**: This salt remains insoluble in water even upon heating. - **Mercury(I) chloride \( \text{Hg}_2Cl_2 \)**: This salt also remains insoluble in water upon heating. 5. **Conclusion**: Since the white precipitate formed from \( M^{n+} \) becomes water soluble upon heating, the only possible cation that fits all these criteria is lead ion \( \text{Pb}^{2+} \). Thus, the metal ion \( M^{n+} \) would be \( \text{Pb}^{2+} \). ### Final Answer: The metal ion \( M^{n+} \) is \( \text{Pb}^{2+} \). ---
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