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How many anions will give colourles acid...

How many anions will give colourles acid vapour/ gas with conc. `H_(2)SO_(4)` on reaction with following gives anions?
`CH_(3)COO^(-) ,Cl^(-),Br^(-),S^(2-),SO_(3)^(2-),BO_(3)^(3-),NO_(2)^(-),C_(2)O_(4)^(2-),I^(-)`

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The correct Answer is:
To determine how many anions will give colorless acid vapors or gases when reacted with concentrated \( H_2SO_4 \), we will analyze each anion provided in the question: 1. **\( CH_3COO^- \) (Acetate Ion)**: - Reaction: \( CH_3COO^- + H_2SO_4 \rightarrow CH_3COOH + SO_4^{2-} \) - Product: Acetic acid (\( CH_3COOH \)) is colorless. - Conclusion: Colorless gas/vapor. 2. **\( Cl^- \) (Chloride Ion)**: - Reaction: \( Cl^- + H_2SO_4 \rightarrow HCl + SO_4^{2-} \) - Product: Hydrochloric acid (HCl) is colorless. - Conclusion: Colorless gas/vapor. 3. **\( Br^- \) (Bromide Ion)**: - Reaction: \( Br^- + H_2SO_4 \rightarrow Br_2 + SO_4^{2-} \) - Product: Bromine gas (\( Br_2 \)) is brown. - Conclusion: Not colorless. 4. **\( S^{2-} \) (Sulfide Ion)**: - Reaction: \( S^{2-} + H_2SO_4 \rightarrow H_2S + SO_4^{2-} \) - Product: Hydrogen sulfide (\( H_2S \)) is colorless. - Conclusion: Colorless gas/vapor. 5. **\( SO_3^{2-} \) (Sulfite Ion)**: - Reaction: \( SO_3^{2-} + H_2SO_4 \rightarrow SO_2 + H_2O \) - Product: Sulfur dioxide (\( SO_2 \)) is colorless. - Conclusion: Colorless gas/vapor. 6. **\( BO_3^{3-} \) (Boron Trioxide Ion)**: - Reaction: \( BO_3^{3-} + H_2SO_4 \rightarrow H_3BO_3 + SO_4^{2-} \) - Product: Boric acid (\( H_3BO_3 \)) is colorless. - Conclusion: Colorless gas/vapor. 7. **\( NO_2^- \) (Nitrite Ion)**: - Reaction: \( NO_2^- + H_2SO_4 \rightarrow NO_2 + H_2O \) - Product: Nitrogen dioxide (\( NO_2 \)) is brown. - Conclusion: Not colorless. 8. **\( C_2O_4^{2-} \) (Oxalate Ion)**: - Reaction: \( C_2O_4^{2-} + H_2SO_4 \rightarrow CO + CO_2 + H_2O \) - Products: Carbon monoxide (\( CO \)) and carbon dioxide (\( CO_2 \)). Carbon dioxide is colorless. - Conclusion: Colorless gas/vapor. 9. **\( I^- \) (Iodide Ion)**: - Reaction: \( I^- + H_2SO_4 \rightarrow I_2 + SO_4^{2-} \) - Product: Iodine gas (\( I_2 \)) is violet. - Conclusion: Not colorless. **Summary of Colorless Gas/Vapor Producing Anions**: - \( CH_3COO^- \) (Acetate) - \( Cl^- \) (Chloride) - \( S^{2-} \) (Sulfide) - \( SO_3^{2-} \) (Sulfite) - \( BO_3^{3-} \) (Boron Trioxide) - \( C_2O_4^{2-} \) (Oxalate) **Total Count**: 6 anions produce colorless gases/vapors. ### Final Answer: **6 anions will give colorless acid vapors/gases with concentrated \( H_2SO_4 \)**.
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