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Incorrect order of ionic size is:...

Incorrect order of ionic size is:

A

`La^(3+) gt Gd^(3+) gt Eu^(3+) gt Lu^(3+)`

B

`V^(2+) gt V^(3+) gt V^(4+) gt V^(5+)`

C

`Tl^(+) gt In^(+) gt Sn^(2+) gt Sb^(3+)`

D

`K^(+) gt Sc^(3+) gt V^(5+) gt Mn^(7+)`

Text Solution

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The correct Answer is:
To determine the incorrect order of ionic size among the given options, we will analyze the trends in ionic sizes based on the periodic table and the properties of the elements involved. ### Step-by-Step Solution: 1. **Understanding Ionic Size Trends:** - Ionic size generally decreases across a period due to increasing nuclear charge, which pulls the electrons closer to the nucleus. - Ionic size increases down a group due to the addition of electron shells, which outweighs the increase in nuclear charge. 2. **Analyzing the Options:** - **Option A:** Lanthanum (La), Gadolinium (Gd), Europium (Eu) - Lanthanum is larger than Gadolinium, and Gadolinium is larger than Europium due to the lanthanide contraction. Therefore, the order La > Gd > Eu is correct, making the statement in the option incorrect. - **Option B:** Vanadium (V²⁺), Vanadium (V³⁺), Vanadium (V⁴⁺), Vanadium (V⁵⁺) - As the positive charge increases, the ionic size decreases. Thus, V²⁺ > V³⁺ > V⁴⁺ > V⁵⁺ is correct. - **Option C:** Thallium (Tl), Indium (In), Tin (Sn), Antimony (Sb) - Thallium is larger than Indium, and Indium is larger than Tin, while Tin is larger than Antimony. This order is consistent with the periodic trends, so it is correct. - **Option D:** Potassium (K), Scandium (Sc), Vanadium (V), Manganese (Mn) - All these elements are in the same period (4th period), and as we move from left to right, ionic size decreases. Thus, the order K > Sc > V > Mn is correct. 3. **Conclusion:** - The only incorrect order of ionic size is found in **Option A**: Lanthanum > Gadolinium > Europium. The correct order should be Lanthanum > Europium > Gadolinium. ### Final Answer: The incorrect order of ionic size is **Option A: Lanthanum > Gadolinium > Europium**.

To determine the incorrect order of ionic size among the given options, we will analyze the trends in ionic sizes based on the periodic table and the properties of the elements involved. ### Step-by-Step Solution: 1. **Understanding Ionic Size Trends:** - Ionic size generally decreases across a period due to increasing nuclear charge, which pulls the electrons closer to the nucleus. - Ionic size increases down a group due to the addition of electron shells, which outweighs the increase in nuclear charge. ...
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VK JAISWAL ENGLISH-PERIODIC PROPERTIES-Level 2
  1. The order of increasing ionic radius of the following is:

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  2. If the ionic radii of K^(+) and F^(-) are nearly the same (i.e., 1.34 ...

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  3. Incorrect order of ionic size is:

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  4. X((g)) to X((g))^(+) +e^(-), " "DeltaH=+720kJ" "mol^(-1) C...

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  5. Consider the followng changes: M(s) to M(g) . . . (1) M(s) to M^(...

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  6. The correct order of second I.E. of C, N, O and F are in the order:

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  7. Which is the correct order of ionization energies?

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  8. Which of the following statements is incorrect?

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  9. First ionization energy is the lowest with:

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  10. The incorrect among the following is:

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  11. The correct values of ionization enthalpies (in kJ mol^(-1)) of Si, P,...

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  12. The third ionization enthalpy is maximum for

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  13. Consider the following ionisation reactions: If monovalent positi...

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  14. The incorrect statement is:

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  15. First three ionisation energies (in kJ/mol) of three representative el...

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  16. Which of the following statement is correct regarding following specie...

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  17. The correct order of increasing electron affinity of the following ele...

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  18. The second electron gain enthalpies (in kJ mol^(-1)) of oxygen and sul...

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  19. Which of the following statement is correct?

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  20. Which of the following statements is incorrect?

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