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Aqueous solutions of two compounds M(1)-...

Aqueous solutions of two compounds `M_(1)-O-H and M_(2)-O-H` are prepared in two different beakers. If, the electronegativity of `M_(1)=3.4,M_(2)=1.2, O=3.5 and H=2.1`, then the nature of two solutions will be respectively:

A

acidic, basic

B

acidic, acidic

C

basic, acidic

D

basic, basic

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To determine the nature of the aqueous solutions of the compounds \( M_1OH \) and \( M_2OH \), we will analyze the electronegativity values of the elements involved and the resulting bond polarities. ### Step-by-Step Solution: 1. **Identify the Electronegativity Values:** - Given values: - Electronegativity of \( M_1 = 3.4 \) - Electronegativity of \( M_2 = 1.2 \) - Electronegativity of \( O = 3.5 \) - Electronegativity of \( H = 2.1 \) 2. **Calculate the Electronegativity Differences:** - For \( M_1OH \): - Difference between \( M_1 \) and \( O \): \[ |3.4 - 3.5| = 0.1 \] - Difference between \( O \) and \( H \): \[ |3.5 - 2.1| = 1.4 \] - For \( M_2OH \): - Difference between \( M_2 \) and \( O \): \[ |1.2 - 3.5| = 2.3 \] - Difference between \( O \) and \( H \): \[ |3.5 - 2.1| = 1.4 \] 3. **Analyze the Bond Polarities:** - For \( M_1OH \): - The bond \( M_1-O \) has a small electronegativity difference (0.1), indicating a covalent bond. - The bond \( O-H \) has a larger electronegativity difference (1.4), indicating a polar covalent bond. - Since \( O \) is more electronegative than \( H \), it will attract the shared electrons more, leading to the release of \( H^+ \) ions in solution. Thus, \( M_1OH \) will be **acidic**. - For \( M_2OH \): - The bond \( M_2-O \) has a large electronegativity difference (2.3), indicating a highly polar bond, likely ionic. - The bond \( O-H \) remains the same with a difference of 1.4. - The high electronegativity difference suggests that the \( M_2-O \) bond will break, leading to the release of \( OH^- \) ions in solution. Thus, \( M_2OH \) will be **basic**. 4. **Conclusion:** - The nature of the two solutions is: - \( M_1OH \) is **acidic**. - \( M_2OH \) is **basic**. ### Final Answer: The nature of the two solutions will be respectively: **acidic** for \( M_1OH \) and **basic** for \( M_2OH \). ---

To determine the nature of the aqueous solutions of the compounds \( M_1OH \) and \( M_2OH \), we will analyze the electronegativity values of the elements involved and the resulting bond polarities. ### Step-by-Step Solution: 1. **Identify the Electronegativity Values:** - Given values: - Electronegativity of \( M_1 = 3.4 \) - Electronegativity of \( M_2 = 1.2 \) ...
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