Home
Class 12
CHEMISTRY
Assertion: magnitude of electron gain en...

Assertion: magnitude of electron gain enthalpy of oxygen is less than that of fluorine but greater than that of nitrogen.
Reason: Ionisation enthalpy order is as follows: `N gt O lt F`.

A

If both assertion and reason are true annd the reason is the correct explanation of assertion

B

If both assertion and reason are true but reason is not the correct explanation of assertion

C

If assertion is true but the reason is false

D

if assertion is false but the reason is true

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the assertion and reason statements provided. ### Step 1: Understand the Assertion The assertion states that the magnitude of electron gain enthalpy of oxygen is less than that of fluorine but greater than that of nitrogen. - **Electron Gain Enthalpy**: This is the energy change when an electron is added to a neutral atom in the gas phase. A more negative value indicates a greater tendency to gain an electron. #### Evaluation of Assertion: 1. **Fluorine**: Has the highest electron gain enthalpy because it is highly electronegative and has a small atomic size, making it more favorable to gain an electron. 2. **Oxygen**: Has a relatively high electron gain enthalpy, but it is less than that of fluorine due to its larger atomic size and the presence of electron-electron repulsion in its valence shell. 3. **Nitrogen**: Has the least electron gain enthalpy because it has a half-filled p subshell configuration (2p3), which is stable and does not favor gaining an additional electron. Thus, the assertion is **true**: - Electron gain enthalpy order: \( \text{E}_a(\text{F}) > \text{E}_a(\text{O}) > \text{E}_a(\text{N}) \). ### Step 2: Understand the Reason The reason states that the ionization enthalpy order is \( \text{N} > \text{O} > \text{F} \). - **Ionization Enthalpy**: This is the energy required to remove the most loosely bound electron from an atom. #### Evaluation of Reason: 1. **Fluorine**: Has the highest ionization enthalpy due to its small size and high electronegativity. 2. **Oxygen**: Has a lower ionization enthalpy than fluorine but higher than nitrogen. 3. **Nitrogen**: Has a half-filled stable electronic configuration, which makes it harder to remove an electron, resulting in a higher ionization enthalpy than expected. The correct order for ionization enthalpy should actually be \( \text{F} > \text{O} > \text{N} \), not \( \text{N} > \text{O} > \text{F} \). Thus, the reason is **false**. ### Conclusion - The assertion is true. - The reason is false. ### Final Answer Both assertion and reason statements are true, but the reason does not correctly explain the assertion. Therefore, the correct option is: **Assertion is true, Reason is false.**
Promotional Banner

Topper's Solved these Questions

  • PERIODIC PROPERTIES

    VK JAISWAL ENGLISH|Exercise SUBJECTIVE PROBLEMS|22 Videos
  • PERIODIC PROPERTIES

    VK JAISWAL ENGLISH|Exercise Level 2|102 Videos
  • PERIODIC PROPERTIES

    VK JAISWAL ENGLISH|Exercise MATCHTHE COLUMN|11 Videos
  • p-BLOCK ELEMENTS

    VK JAISWAL ENGLISH|Exercise SUBJECTIVE PROBLEMS|35 Videos
  • QUALITATIVE INORGANIC ANALYSIS

    VK JAISWAL ENGLISH|Exercise SUBJECTIVE PROBLEMS|4 Videos

Similar Questions

Explore conceptually related problems

Assertion: magnitude of electron gain enthalpy of oxygen is less than that of fluorine but greater than that of nitrogen. Reason: Ionisation enthalpy order is as follows: N gt O lt E .

Electron gain enthalpy of fluorine is less than that of chlorine - explain.

The negative electron gain enthalpy of fluorine is less than that of chlorine.

Why is the electron gain enthalpy of O or F less than that of S or Cl?

The electron gain enthalpy of oxygen is "…………………." than that of sulphur.

Assertion (A) : EA of O is less than that of F but greater than that of N . Reason (R ): IE is as follows: N gt O gt F .

The ionisation enthalpy of Na is less than Ne . Why?

The negative value of electron gain enthalpy is less for fluorine than for chlorine . Why?

Assertion : The electron gain enthalpy of chlorine is less negative than that of fluorine. Reason : The fluorine atom is much smaller in size than that of chlorine.

Assertion: The electron affinity of chlorine is greater than that of fluorine. Reason: Chlorine is more electronegative than fluorine.

VK JAISWAL ENGLISH-PERIODIC PROPERTIES-ASSERTION-REASON TYPE QUESTIONS
  1. He and Be both have the same outer electronic configuration like ns^(2...

    Text Solution

    |

  2. Assertion: The first ionisation enthalpy of aluminium is lower than th...

    Text Solution

    |

  3. Assertion: In CsF, salt, size of Cs^(+) is slight higher than size of ...

    Text Solution

    |

  4. Assertion: First electron affinity of all elements is positive. Reas...

    Text Solution

    |

  5. Assertion: helium atom has highest ionisation energy among all the ele...

    Text Solution

    |

  6. Assertion: F^(-) ion has highest hydrated radius among the other halid...

    Text Solution

    |

  7. Assertion: magnitude of electron gain enthalpy of oxygen is less than ...

    Text Solution

    |

  8. Assertion: Formation of Cl^(-) ion is exothermic wheres O^(2-) ion for...

    Text Solution

    |

  9. Assertion: The electron gain enthalpy of N is +ve while that of P is -...

    Text Solution

    |

  10. Assertion: The formation of F((g))^(-) from F((g)) is exothermic, wher...

    Text Solution

    |

  11. Assertion: Na^(+) and Al^(3+) are isoelectronic but ionic radius Al^3+...

    Text Solution

    |

  12. Assertion: The third period contains only 8 electrons and not 18 like ...

    Text Solution

    |

  13. Assertion: Cs and F(2) combines violently to form CsF. Reason: Cs is...

    Text Solution

    |

  14. Assertion: Second E.A. for halogens is almost zero. Reason: Fluorine...

    Text Solution

    |

  15. Assertion: F atom has less electron afffinity than Cl atom. Reason: ...

    Text Solution

    |

  16. Assertion: Among the halogens bond energy of F(2) is minimum. Reason...

    Text Solution

    |

  17. Assertion: The first ionization energy of Be is greater than that of B...

    Text Solution

    |

  18. Assertion: Noble gases have highest ionization enthalpies in their res...

    Text Solution

    |

  19. He and Be both have the same outer electronic configuration like ns^(2...

    Text Solution

    |

  20. Assertion: the first enthalpy of aluminium is lower than that of magne...

    Text Solution

    |