Home
Class 12
CHEMISTRY
Assertion: Formation of Cl^(-) ion is ex...

Assertion: Formation of `Cl^(-)` ion is exothermic wheres `O^(2-)` ion formation is endothermic.
Reason: `EA_(2)` of oxygen is endothermic and greater than its exothermic `EA_(1)` value of oxygen.

A

If both assertion and reason are true annd the reason is the correct explanation of assertion

B

If both assertion and reason are true but reason is not the correct explanation of assertion

C

If assertion is true but the reason is false

D

if assertion is false but the reason is true

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the assertion and the reason provided in the question regarding the formation of ions and their electron affinity. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that the formation of the `Cl^(-)` ion is exothermic, while the formation of the `O^(2-)` ion is endothermic. - Exothermic processes release energy (negative ΔH), while endothermic processes absorb energy (positive ΔH). 2. **Formation of `Cl^(-)` Ion**: - Chlorine (Cl) has a high electron affinity, meaning it readily gains an electron to form `Cl^(-)`. - The process can be represented as: \[ \text{Cl} + e^- \rightarrow \text{Cl}^- \] - This reaction releases energy, indicating that it is exothermic. Therefore, the assertion is correct for chlorine. 3. **Formation of `O^(2-)` Ion**: - Oxygen (O) can gain two electrons to form `O^(2-)`. The process occurs in two steps: 1. The first step is the formation of `O^(-)`: \[ \text{O} + e^- \rightarrow \text{O}^- \] This step is exothermic as energy is released. 2. The second step involves adding another electron to form `O^(2-)`: \[ \text{O}^- + e^- \rightarrow \text{O}^{2-} \] This step is endothermic because the added electron experiences repulsion from the already present electrons, requiring energy input to overcome this repulsion. 4. **Understanding the Reason**: - The reason states that the second electron affinity (`EA_2`) of oxygen is endothermic and greater than the first electron affinity (`EA_1`). - This is true because the first electron affinity (`EA_1`) is exothermic (energy is released), while the second electron affinity (`EA_2`) is endothermic (energy is required). 5. **Conclusion**: - Both the assertion and the reason are true. The formation of `Cl^(-)` is indeed exothermic, and the formation of `O^(2-)` is endothermic due to the nature of electron repulsion and energy requirements in the second electron affinity. ### Final Answer: Both the assertion and the reason are true.
Promotional Banner

Topper's Solved these Questions

  • PERIODIC PROPERTIES

    VK JAISWAL ENGLISH|Exercise SUBJECTIVE PROBLEMS|22 Videos
  • PERIODIC PROPERTIES

    VK JAISWAL ENGLISH|Exercise Level 2|102 Videos
  • PERIODIC PROPERTIES

    VK JAISWAL ENGLISH|Exercise MATCHTHE COLUMN|11 Videos
  • p-BLOCK ELEMENTS

    VK JAISWAL ENGLISH|Exercise SUBJECTIVE PROBLEMS|35 Videos
  • QUALITATIVE INORGANIC ANALYSIS

    VK JAISWAL ENGLISH|Exercise SUBJECTIVE PROBLEMS|4 Videos

Similar Questions

Explore conceptually related problems

Formation of F^(-) is exothermic but formation of O2^(-) is endothermic. Explain in two or three sentences.

Assertion: The formation of F_((g))^(-) from F_((g)) is exothermic, whereas that of O_((g))^(2-) from O_((g)) is endotherrmic. Reason: The addition of second electron to a monovalent anion is difficult because both have the same charge and experience more repulsion.

Is formation of ozone from oxygen an endothermic or exothermic reaction?

The formation of water from H_(2)(g) and O_(2)(g) is an exothermic process because :

Assertion (A) : H_2O is a linear molecule. Reason (R) : Oxygen is sp^3 hybridised.

Why MgO exist as Mg^(2+)O^(2-) not as Mg^(o+)O^(ɵ) whereas the formation of Mg^(2+) from Mg requires more energy than formation of Mg^(o+) and formation of O^(ɵ) from O is exothermic whereas the formation of O^(2-) is endothermic .

Assertion (A) : The value of K increases with increase in temperature in case of endothermic reaction Reason (R) : The increase in temperature shifts the equilibrium in the backward direction in case of exothermic reaction.

Dimerisation of NO_2, is an exothermic reaction. If enthalpy of reaction is /_\H, then the minimum value of activation energy for forward reaction (E_a) will be

Assertion(A) Electrolysis of NaCl solution gives chlorine at anode instead of O_(2) . Reason(R) Formation of oxygen at anode requires over voltage.

Assertion : The higher concentration of O_2 in the atmosphere is inhibitory to photosynthesis. Reason; Rubisco binds to oxygen at high partial pressure of oxygen

VK JAISWAL ENGLISH-PERIODIC PROPERTIES-ASSERTION-REASON TYPE QUESTIONS
  1. He and Be both have the same outer electronic configuration like ns^(2...

    Text Solution

    |

  2. Assertion: The first ionisation enthalpy of aluminium is lower than th...

    Text Solution

    |

  3. Assertion: In CsF, salt, size of Cs^(+) is slight higher than size of ...

    Text Solution

    |

  4. Assertion: First electron affinity of all elements is positive. Reas...

    Text Solution

    |

  5. Assertion: helium atom has highest ionisation energy among all the ele...

    Text Solution

    |

  6. Assertion: F^(-) ion has highest hydrated radius among the other halid...

    Text Solution

    |

  7. Assertion: magnitude of electron gain enthalpy of oxygen is less than ...

    Text Solution

    |

  8. Assertion: Formation of Cl^(-) ion is exothermic wheres O^(2-) ion for...

    Text Solution

    |

  9. Assertion: The electron gain enthalpy of N is +ve while that of P is -...

    Text Solution

    |

  10. Assertion: The formation of F((g))^(-) from F((g)) is exothermic, wher...

    Text Solution

    |

  11. Assertion: Na^(+) and Al^(3+) are isoelectronic but ionic radius Al^3+...

    Text Solution

    |

  12. Assertion: The third period contains only 8 electrons and not 18 like ...

    Text Solution

    |

  13. Assertion: Cs and F(2) combines violently to form CsF. Reason: Cs is...

    Text Solution

    |

  14. Assertion: Second E.A. for halogens is almost zero. Reason: Fluorine...

    Text Solution

    |

  15. Assertion: F atom has less electron afffinity than Cl atom. Reason: ...

    Text Solution

    |

  16. Assertion: Among the halogens bond energy of F(2) is minimum. Reason...

    Text Solution

    |

  17. Assertion: The first ionization energy of Be is greater than that of B...

    Text Solution

    |

  18. Assertion: Noble gases have highest ionization enthalpies in their res...

    Text Solution

    |

  19. He and Be both have the same outer electronic configuration like ns^(2...

    Text Solution

    |

  20. Assertion: the first enthalpy of aluminium is lower than that of magne...

    Text Solution

    |