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BeCl(2) is not isostructural with...

`BeCl_(2)` is not isostructural with

A

`IC l_(2)^(-)`

B

`C_(2)H_(2)`

C

`XeF_(2)`

D

`GeCl_(2)`

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The correct Answer is:
To determine which molecule is not isostructural with BeCl₂, we need to analyze the structure and hybridization of each given option. ### Step-by-Step Solution: 1. **Understanding BeCl₂ Structure:** - Beryllium chloride (BeCl₂) has a linear structure. - Beryllium (Be) has 2 valence electrons and forms 2 bonds with chlorine (Cl) atoms, resulting in 0 lone pairs. - The hybridization of BeCl₂ is sp, leading to a linear geometry. 2. **Analyzing ICl₂⁻:** - Iodine (I) has 7 valence electrons. With a negative charge, it has 8 electrons. - It forms 2 bonds with Cl atoms and has 3 lone pairs. - The hybridization is sp³d (2 bond pairs + 3 lone pairs), resulting in a linear structure due to the presence of only 2 bond pairs. 3. **Analyzing C₂H₂:** - In ethyne (C₂H₂), each carbon atom forms a triple bond with the other carbon and single bonds with hydrogen atoms. - The hybridization of carbon in C₂H₂ is sp, leading to a linear structure. 4. **Analyzing XC-F₂:** - Assuming XC is a generic element with 8 valence electrons, it forms 2 bonds with fluorine (F) and has 3 lone pairs. - The hybridization is sp³d (2 bond pairs + 3 lone pairs), resulting in a linear structure. 5. **Analyzing GeCl₂:** - Germanium (Ge) has 4 valence electrons and forms 2 bonds with Cl atoms, resulting in 1 lone pair. - The hybridization is sp² (2 bond pairs + 1 lone pair), leading to a bent or V-shaped structure. ### Conclusion: - BeCl₂ is linear with sp hybridization. - ICl₂⁻, C₂H₂, and XC-F₂ are also linear. - GeCl₂ is not linear; it has a bent shape due to sp² hybridization. Thus, **GeCl₂ is not isostructural with BeCl₂**.

To determine which molecule is not isostructural with BeCl₂, we need to analyze the structure and hybridization of each given option. ### Step-by-Step Solution: 1. **Understanding BeCl₂ Structure:** - Beryllium chloride (BeCl₂) has a linear structure. - Beryllium (Be) has 2 valence electrons and forms 2 bonds with chlorine (Cl) atoms, resulting in 0 lone pairs. - The hybridization of BeCl₂ is sp, leading to a linear geometry. ...
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VK JAISWAL ENGLISH-CHEMICAL BONDING (BASIC)-SUBJECTIVE PROBLEMS
  1. BeCl(2) is not isostructural with

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  2. Consider following compounds A to E : (A) XeF(n) " " (B) XeF((n+1)...

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  3. Consider the following five group (According to modern periodic table)...

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  4. Consider the following species and find out total number of species wh...

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  5. Consider the following table regarding interhalogen compounds, XY(n) (...

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  6. What is covalency of chlorine atom in second excited state ?

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  7. Sum of sigma and pi bonds in NH(4)^(+) cation is ..

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  8. Calculate the value of X-Y, for XeOF(4). (X=Number of sigma bond pair ...

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  9. The molecule ABn is planar with six pairs of electrons around A in the...

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  10. Calculate value of (X+Y+Z)/(10), here X is O-N-O bond angle in NO(3)^(...

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  11. Calculate x+y+z for H(3)PO(3) acid, where x is no. of lone pairs, y is...

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  12. How many right angle, bond angles are present in TeF(5)^(-) molecular ...

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  13. How may possible angle FSeF bond angles are present in SeF(4) molecule...

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  14. In IF(6)^(-) and TeF(5)^(-), sum of axial d-orbitals which are used in...

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  15. Among the following, total no. of planar species is : (i) SF(4) " "...

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  16. Calculate the value of " x+y-z" here x,y and z are total number of non...

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  17. Consider the following table Then calculate value of "p+q+r-s-t".

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  18. In phosphorus acid, if X is number of non bonding electron pairs. Y is...

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  19. Calculate the number of p(pi)-d(pi) bond(s) present in SO(4)^(2-) :

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  20. Sum of sigma and pi bonds in NH(4)^(+) cation is ..

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  21. Consider the following orbitals (i)3p(x) (ii)4d(z^(2)) (iii)3d(x^(2)...

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