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What is the shape of the ClF(3) molecule...

What is the shape of the `ClF_(3)` molecule?

A

Trigonal planar

B

Trigonal pyramidal

C

T-shaped

D

Tetrahedral

Text Solution

AI Generated Solution

The correct Answer is:
To determine the shape of the ClF₃ molecule, we can follow these steps: ### Step 1: Determine the Valence Electrons Chlorine (Cl) is in Group 17 of the periodic table, which means it has 7 valence electrons. Each fluorine (F) atom contributes 1 valence electron, and since there are 3 fluorine atoms, they contribute a total of 3 electrons. Therefore, the total number of valence electrons in ClF₃ is: \[ 7 \, (\text{from Cl}) + 3 \times 1 \, (\text{from F}) = 10 \, \text{valence electrons} \] ### Step 2: Draw the Lewis Structure In the Lewis structure of ClF₃, chlorine is the central atom. It forms three single bonds with the three fluorine atoms. After forming these bonds, we have: - 3 bonds (3 pairs of electrons) used, which accounts for 6 electrons. - This leaves us with 4 electrons (2 lone pairs) remaining on the chlorine atom. ### Step 3: Calculate the Steric Number The steric number is calculated as the sum of the number of sigma bonds and the number of lone pairs around the central atom. In ClF₃: - There are 3 sigma bonds (one for each Cl-F bond). - There are 2 lone pairs on the chlorine atom. Thus, the steric number is: \[ \text{Steric Number} = 3 \, (\text{sigma bonds}) + 2 \, (\text{lone pairs}) = 5 \] ### Step 4: Determine the Hybridization The hybridization corresponding to a steric number of 5 is sp³d. ### Step 5: Identify the Geometry With sp³d hybridization, the geometry of the molecule is trigonal bipyramidal. ### Step 6: Determine the Molecular Shape However, since there are 2 lone pairs, they will occupy the equatorial positions in the trigonal bipyramidal geometry to minimize repulsion. This results in a T-shaped molecular geometry for ClF₃. ### Final Answer The shape of the ClF₃ molecule is T-shaped. ---

To determine the shape of the ClF₃ molecule, we can follow these steps: ### Step 1: Determine the Valence Electrons Chlorine (Cl) is in Group 17 of the periodic table, which means it has 7 valence electrons. Each fluorine (F) atom contributes 1 valence electron, and since there are 3 fluorine atoms, they contribute a total of 3 electrons. Therefore, the total number of valence electrons in ClF₃ is: \[ 7 \, (\text{from Cl}) + 3 \times 1 \, (\text{from F}) = 10 \, \text{valence electrons} \] ...
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VK JAISWAL ENGLISH-CHEMICAL BONDING (BASIC)-SUBJECTIVE PROBLEMS
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  2. Consider following compounds A to E : (A) XeF(n) " " (B) XeF((n+1)...

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  3. Consider the following five group (According to modern periodic table)...

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