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Assertion : Xe-atom in XeF(2) assumes sp...

Assertion : Xe-atom in `XeF_(2)` assumes sp-hybrid state.
Reason : `XeF_(2)` molecule does not follow octet rule.

A

If assertion is true but the reason is false

B

If assertion is false but reason is true

C

IF both assertion and reason are true and the reason is the correct explanation of assertion

D

If both assertion and reason are true but reason is not the correct explanation of assertion

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the assertion and reason provided in the question, we will break down the information step by step. ### Step 1: Understanding the Assertion The assertion states that the Xe atom in \(XeF_2\) assumes an sp-hybrid state. - **Hybridization** is determined by the steric number, which is the sum of the number of sigma bonds and lone pairs around the central atom. - In \(XeF_2\), xenon (Xe) is the central atom bonded to two fluorine (F) atoms. ### Step 2: Calculating the Steric Number To find the steric number for xenon in \(XeF_2\): - **Bond Pairs**: There are 2 bond pairs (due to the two Xe-F bonds). - **Lone Pairs**: Xenon has 4 valence electrons and forms 2 bonds with fluorine, leaving it with 3 lone pairs. Now, we calculate the steric number: \[ \text{Steric Number} = \text{Number of Bond Pairs} + \text{Number of Lone Pairs} = 2 + 3 = 5 \] ### Step 3: Determining Hybridization The hybridization corresponding to a steric number of 5 is **sp³d**, not sp. - Therefore, the assertion that Xe assumes an sp-hybrid state is **false**. ### Step 4: Understanding the Reason The reason states that the \(XeF_2\) molecule does not follow the octet rule. - The octet rule states that atoms tend to form compounds in ways that give them eight valence electrons. - In \(XeF_2\), xenon has 2 bond pairs and 3 lone pairs, leading to a total of 10 electrons around xenon (6 from lone pairs and 4 from bond pairs). ### Step 5: Conclusion Since \(XeF_2\) has 10 electrons around xenon, it does not follow the octet rule, which makes the reason **true**. ### Final Evaluation - **Assertion**: False (Xe is sp³d hybridized, not sp). - **Reason**: True (XeF₂ does not follow the octet rule). Thus, the correct answer is that the assertion is false, but the reason is true.
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