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Consider the following species NO(3)^(-)...

Consider the following species `NO_(3)^(-), SO_(4)^(2-), ClO_(3)^(-),SO_(3), PO_(4)^(3-), XeO_(3),CO_(3)^(2-), SO_(3)^(2-)`
Then calculate value of |x-y|, where
x : Total number of species which have bond order 1.5 or greater than 1.5
y : Total number of species which have bond order less than 1.5

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To solve the problem, we need to calculate the bond order of each species listed and then determine how many of these species have a bond order of 1.5 or greater (denoted as x) and how many have a bond order less than 1.5 (denoted as y). Finally, we will calculate the absolute difference |x - y|. ### Step 1: Determine the bond order for each species 1. **NO₃⁻ (Nitrate Ion)**: - Structure: Resonance with one double bond and two single bonds. - Bond Order Calculation: \[ \text{Bond Order} = \frac{\text{Number of Bonds}}{\text{Number of Bonding Pairs}} = \frac{2 + 1}{3} = 1.33 \] 2. **SO₄²⁻ (Sulfate Ion)**: - Structure: Resonance with two double bonds and two single bonds. - Bond Order Calculation: \[ \text{Bond Order} = \frac{4}{4} = 1.5 \] 3. **ClO₃⁻ (Chlorate Ion)**: - Structure: Resonance with one double bond and two single bonds. - Bond Order Calculation: \[ \text{Bond Order} = \frac{2 + 1}{3} = 1.66 \] 4. **SO₃ (Sulfur Trioxide)**: - Structure: One double bond with each of the three oxygen atoms. - Bond Order Calculation: \[ \text{Bond Order} = 2 \] 5. **PO₄³⁻ (Phosphate Ion)**: - Structure: Resonance with one double bond and three single bonds. - Bond Order Calculation: \[ \text{Bond Order} = \frac{1 + 3}{4} = 1.25 \] 6. **XeO₃ (Xenon Trioxide)**: - Structure: One double bond with each of the three oxygen atoms. - Bond Order Calculation: \[ \text{Bond Order} = 2 \] 7. **CO₃²⁻ (Carbonate Ion)**: - Structure: Resonance with one double bond and two single bonds. - Bond Order Calculation: \[ \text{Bond Order} = \frac{2 + 1}{3} = 1.33 \] 8. **SO₃²⁻ (Sulfite Ion)**: - Structure: Resonance with one double bond and two single bonds. - Bond Order Calculation: \[ \text{Bond Order} = \frac{2 + 1}{3} = 1.33 \] ### Step 2: Count the number of species with bond orders - **Species with bond order ≥ 1.5 (x)**: - SO₄²⁻ (1.5) - ClO₃⁻ (1.66) - SO₃ (2) - XeO₃ (2) Total: **4 species** (x = 4) - **Species with bond order < 1.5 (y)**: - NO₃⁻ (1.33) - PO₄³⁻ (1.25) - CO₃²⁻ (1.33) - SO₃²⁻ (1.33) Total: **4 species** (y = 4) ### Step 3: Calculate |x - y| \[ |x - y| = |4 - 4| = 0 \] ### Final Answer The value of |x - y| is **0**. ---

To solve the problem, we need to calculate the bond order of each species listed and then determine how many of these species have a bond order of 1.5 or greater (denoted as x) and how many have a bond order less than 1.5 (denoted as y). Finally, we will calculate the absolute difference |x - y|. ### Step 1: Determine the bond order for each species 1. **NO₃⁻ (Nitrate Ion)**: - Structure: Resonance with one double bond and two single bonds. - Bond Order Calculation: \[ ...
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VK JAISWAL ENGLISH-CHEMICAL BONDING (BASIC)-SUBJECTIVE PROBLEMS
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  2. Calculate value of (X+Y+Z)/(10), here X is O-N-O bond angle in NO(3)^(...

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  8. Calculate the value of " x+y-z" here x,y and z are total number of non...

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  9. Consider the following table Then calculate value of "p+q+r-s-t".

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  16. Total number of species which used all three p-orbitals in hybridisati...

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  17. Consider the following species NO(3)^(-), SO(4)^(2-), ClO(3)^(-),SO(3)...

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  18. Consider the following orbitals 3s, 2p(x), 4d(xy),4d(z^(2)), 3d(x^(2)-...

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  19. For the following molecules : PCl(5), BrF(3), IC l(2)^(-), XeF(5)^(-...

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