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Consider following compounds, (i) H(3)...

Consider following compounds,
(i) `H_(3)X-HCS` (ii)`H_(3)Y-NCS` (iii)`(H_(3)Y)_(2)O` (iv)`(H_(2)X)_(2)O`
The incorrect statement regarding given compounds is :

A

If Y is carbon in compounds (ii) and (iv), then both are bent

B

If X is silicon in compounds (i) and (iii), then both are linear

C

If X is carbon and Y is silicon, the compound (i) is more basic than compound (ii)

D

If X is silicon and Y is carbon, then X-O-X bond angle compounds (iii) is greater than Y-O-Y bond angle in compounds (iv)

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The correct Answer is:
To determine the incorrect statement regarding the given compounds, we will analyze each compound and the statements provided. ### Step 1: Identify the Compounds The compounds given are: 1. \( H_3X - HCS \) 2. \( H_3Y - NCS \) 3. \( (H_3Y)_2O \) 4. \( (H_2X)_2O \) ### Step 2: Analyze Each Statement We need to analyze the statements regarding the elements X and Y in the compounds. #### Statement Analysis: 1. **Statement 1:** Y is carbon in compound 1. - If Y is carbon, then \( H_3Y \) would be \( H_3C \), and \( HCS \) would imply a structure with carbon and sulfur. This statement is plausible. 2. **Statement 2:** X is silicon in compound 1. - If X is silicon, then \( H_3X \) would be \( H_3Si \). This compound can form a linear structure with \( HCS \). This statement is also plausible. 3. **Statement 3:** If X is carbon and Y is silicon, compound 1 is more basic than compound 2. - If X is carbon and Y is silicon, then \( H_3C - HCS \) and \( H_3Si - NCS \) are compared. Basicity generally decreases down the group in the periodic table, making this statement likely incorrect. 4. **Statement 4:** If X is silicon and Y is carbon, then the bond angle \( X-O-X \) is greater than \( X-O-Y \). - If X is silicon and Y is carbon, both compounds would have similar bond angles due to their linear structure. This statement is also likely incorrect. ### Step 3: Conclusion From the analysis, the incorrect statement is: - **Statement 3:** If X is carbon and Y is silicon, compound 1 is more basic than compound 2. ### Final Answer The incorrect statement regarding the given compounds is **Statement 3**. ---

To determine the incorrect statement regarding the given compounds, we will analyze each compound and the statements provided. ### Step 1: Identify the Compounds The compounds given are: 1. \( H_3X - HCS \) 2. \( H_3Y - NCS \) 3. \( (H_3Y)_2O \) 4. \( (H_2X)_2O \) ...
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