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Nodal planes of pi-bonds in CH(2)=C=C=CH...

Nodal planes of `pi`-bonds in `CH_(2)=C=C=CH_(2)` are located in,

A

All are in molecular plane

B

Two in molecular plane and one in a plane perpendicular to molecular plane which contains C-C sigma-bond

C

On is molecular plane and two in plane perpendicular to molecular plane which contains C-C sigma-bonds

D

Two in molecular plane and one in a perpendicular to molecular plane which bisects C-C sigma-bonds at right angle.

Text Solution

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The correct Answer is:
To determine the nodal planes of the π-bonds in the compound CH₂=C=C=CH₂, we need to analyze the structure and bonding of the molecule step by step. ### Step 1: Draw the Structure of the Molecule The first step is to visualize the structure of the molecule. CH₂=C=C=CH₂ consists of two terminal carbon atoms (each bonded to two hydrogen atoms) and two central carbon atoms that are double-bonded to each other. **Hint:** Start by sketching the molecule to understand its geometry and bonding. ### Step 2: Identify the Types of Bonds In the structure, we have: - Sigma (σ) bonds: These are single bonds formed by the head-on overlap of atomic orbitals. In this case, the C-H and C=C bonds are σ bonds. - Pi (π) bonds: These are formed by the side-to-side overlap of p orbitals. The double bonds between the central carbons (C=C) consist of one σ bond and one π bond. **Hint:** Remember that each double bond consists of one σ bond and one π bond. ### Step 3: Determine the Nodal Planes of the π-bonds For π-bonds, the nodal planes are the planes where the probability of finding an electron is zero. In the case of the π-bonds in the molecule: - The π-bond between the first and second carbon (C1=C2) has a nodal plane that is perpendicular to the plane of the molecule. - The π-bond between the second and third carbon (C2=C3) also has a nodal plane that is perpendicular to the plane of the molecule. **Hint:** Nodal planes for π-bonds are typically perpendicular to the bond axis. ### Step 4: Identify the Orientation of the Nodal Planes The nodal planes of the π-bonds are located: 1. One nodal plane between the first and second carbons (C1=C2). 2. Another nodal plane between the second and third carbons (C2=C3). These nodal planes are oriented in such a way that they are perpendicular to the plane of the molecule, which contains the σ-bonds. **Hint:** Visualize the orientation of the bonds and how the nodal planes relate to them. ### Conclusion In summary, the nodal planes of the π-bonds in CH₂=C=C=CH₂ are located in planes that are perpendicular to the molecular plane containing the σ-bonds. **Final Answer:** The nodal planes of the π-bonds in CH₂=C=C=CH₂ are located in planes perpendicular to the molecular plane containing the σ-bonds.

To determine the nodal planes of the π-bonds in the compound CH₂=C=C=CH₂, we need to analyze the structure and bonding of the molecule step by step. ### Step 1: Draw the Structure of the Molecule The first step is to visualize the structure of the molecule. CH₂=C=C=CH₂ consists of two terminal carbon atoms (each bonded to two hydrogen atoms) and two central carbon atoms that are double-bonded to each other. **Hint:** Start by sketching the molecule to understand its geometry and bonding. ### Step 2: Identify the Types of Bonds ...
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