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The incorrect statement regarding O(SiH(...

The incorrect statement regarding `O(SiH_(3))_(2) and OCl_(2)` molecule is/are

A

The strength of back bonding is more in `O(SiH_(3))_(2)` molecule than `Ocl_(2)` molecule

B

`Si-O-Si` bond angle in `O(SiH_(3))_(2)` is greater than `Cl-O-Cl` bond angle in `OCl_(2)`

C

The nature of back in both molecules is `2p_(x)-3d_(pi)`

D

Hybridisation of central O-atom in both molecules is same

Text Solution

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The correct Answer is:
D

hybridisation of O-atom : `sp^(2)` due to more extent of `(2p_(pi)-3d_(pi))` back bonding.
Hybridisation of O-atom remains `sp^(3)`, becouse of less effective `(2p_(pi)-3d_(pi))` back bonding due to d-orbital resonance
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VK JAISWAL ENGLISH-CHEMICAL BONDING (ADVANCED)-Level 2
  1. On heating to 400-500^(@)C, relatively unstable hydrides and carbonate...

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  2. Both N(SiH(3))(3) and NH(SiH(3))(2) compounds have trigonal planar ske...

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  3. The incorrect statement regarding O(SiH(3))(2) and OCl(2) molecule is/...

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  4. Among following molecule N-Si bond length is shortest:

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  5. Which of the following molecule has weakest (ppi-dpi) back bonding?

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  6. The geometry with respect to the central atom of the following molecul...

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  7. Incorrect statement regarding BF(3)NH(3) molecule is :

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  8. In which of the following molecules mu(oberved) is found to be greater...

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  9. Among the following, the molecule with the highest dipole moment is :

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  10. Which of the following is wheat fruit?

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  11. Which of the following is wheat fruit?

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  12. The bond having the minimum bond energy is :

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  13. The correct increasing order of extent of hydrolysis is

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  14. Inorganic benzene reacts with HCl to form a compounds B(3)N(3)H(9)Cl(...

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  15. Select the correct statements about hydrolysis of BCl(3) and NCl(3):

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  16. The incorrect statement regarding molecular orbital (s) is :

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  17. Which of the following species absorb maximum energy in its HOMO-LUMO ...

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  18. If P to T are second period p-block elements then which of the followi...

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  19. Which of the following facts given is not correct? (I) Bond length o...

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  20. N(2) and O(2) are converted to monocations N(2)^(+) and O(2)^(+) respe...

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