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Which of the following facts given is no...

Which of the following facts given is not correct?
(I) Bond length order, `H_(2)^(-)-H_(2)^(+)gtH_(2)`
(II) `O_(2)^(+), NO, N_(2)^(-)` have same bond order of `2(1)/(2)`
(II) Bond order can assume any value including zero upto four
(IV) `NO_(3)^(-) and BO_(3)^(-)` have same order for `X-O` bond (where X is central atom)

A

I, II and III

B

I and IV

C

II and IV

D

I and II

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze each of the statements provided and determine which one is incorrect. ### Step-by-Step Solution: 1. **Statement I: Bond length order, H2^(-) > H2^(+) > H2** - **Analysis**: - H2 has the highest bond order (1), hence it has the shortest bond length. - H2^(-) has a bond order of 0.5, and H2^(+) also has a bond order of 0.5. - Therefore, the bond length order should be H2 < H2^(-) = H2^(+). - Thus, this statement is **incorrect** because it suggests the opposite order. 2. **Statement II: O2^(+), NO, N2^(-) have the same bond order of 2.5** - **Analysis**: - O2^(+) has 15 electrons, which gives it a bond order of 2.5. - NO has 15 electrons as well, giving it a bond order of 2.5. - N2^(-) has 15 electrons, resulting in a bond order of 2.5. - Therefore, this statement is **correct**. 3. **Statement III: Bond order can assume any value including zero up to four** - **Analysis**: - Bond order can range from 0 (no bond) to a maximum of 3 (for triple bonds). - It cannot reach 4; hence, this statement is **incorrect**. 4. **Statement IV: NO3^(-) and BO3^(-) have the same order for X-O bond** - **Analysis**: - Both NO3^(-) and BO3^(-) have resonance structures that can be analyzed. - The bond order for the X-O bond in both cases is indeed the same due to resonance. - Therefore, this statement is **correct**. ### Conclusion: The statements that are incorrect are **I** and **III**. However, since the question asks for which fact is not correct, we can conclude that the most clearly incorrect statement is **III**. ### Final Answer: The statement that is not correct is **III**: "Bond order can assume any value including zero up to four."
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