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Assertion : Nitrogen in inactive at room...

Assertion : Nitrogen in inactive at room temperature but becomes reactive at elevated temperature (on heating or in the presence of catalyst).
Reason : In nitrogen molecule, there is delocalization electrons.

A

If assertion is true but the reason is false

B

If assertion is false but reason is true

C

If both assertion and reason are true and the reason is the correct explanation of assertion

D

If both assertion and reason are true and the reason is not the correct explanation of assertion

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The correct Answer is:
### Step-by-Step Solution 1. **Understanding the Assertion**: - The assertion states that nitrogen is inactive at room temperature but becomes reactive at elevated temperatures or in the presence of a catalyst. This is true because nitrogen (N₂) has a very strong triple bond between the two nitrogen atoms, making it relatively inert under normal conditions. **Hint**: Consider the strength of the bonds in nitrogen and how temperature affects molecular activity. 2. **Analyzing the Structure of Nitrogen**: - Nitrogen has five valence electrons. To achieve a stable octet, two nitrogen atoms share three pairs of electrons, forming a strong triple bond (N≡N). This bond is very stable and requires significant energy to break. **Hint**: Recall the concept of covalent bonding and how atoms achieve stability through electron sharing. 3. **Effect of Temperature and Catalysts**: - At elevated temperatures or in the presence of a catalyst, the energy provided can weaken the triple bond. This allows nitrogen to react with other substances, such as oxygen, to form compounds like nitrogen oxides. **Hint**: Think about how increasing temperature can provide energy to overcome activation barriers in chemical reactions. 4. **Understanding the Reason**: - The reason given states that there is delocalization of electrons in the nitrogen molecule. This is incorrect. In the nitrogen molecule (N₂), the electrons are localized in the triple bond and are not delocalized. Delocalization typically occurs in molecules with resonance structures or in systems with conjugated double bonds. **Hint**: Differentiate between localized and delocalized electrons and consider the structure of nitrogen. 5. **Conclusion**: - The assertion is true: nitrogen is inactive at room temperature but becomes reactive at elevated temperatures or in the presence of a catalyst. The reason is false because there is no delocalization of electrons in the nitrogen molecule. **Final Answer**: The assertion is true, but the reason is false. Therefore, the correct option is option number one.
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