Home
Class 12
CHEMISTRY
Assertion: C(3)O(2) has linear structure...

Assertion: `C_(3)O_(2)` has linear structure.
Reason: Each carbon atom in `C_(3)O_(2)` in `sp` -hydridized.

A

If assertion is true but the reason is false

B

If assertion is false but reason is true

C

If both assertion and reason are true and the reason is the correct explanation of assertion

D

If both assertion and reason are true and the reason is not the correct explanation of assertion

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the assertion and reason provided in the question regarding the compound \( C_3O_2 \), we will break down the information step by step. ### Step 1: Understanding the Assertion The assertion states that \( C_3O_2 \) has a linear structure. - **Explanation**: A linear structure implies that the bond angles between the atoms are 180 degrees. This is typically seen in molecules where the central atom is surrounded by two other atoms with no lone pairs, leading to a straight-line arrangement. ### Step 2: Analyzing the Reason The reason provided states that each carbon atom in \( C_3O_2 \) is in an \( sp \) hybridized state. - **Explanation**: Hybridization is a concept used to describe the mixing of atomic orbitals to form new hybrid orbitals. The \( sp \) hybridization occurs when one s orbital and one p orbital mix to form two equivalent \( sp \) hybrid orbitals. This type of hybridization is associated with a linear geometry and a steric number of 2 (which is the sum of sigma bonds and lone pairs). ### Step 3: Determining the Hybridization of Carbon Atoms To determine the hybridization of the carbon atoms in \( C_3O_2 \): 1. **Count the Valence Electrons**: Each carbon atom has 4 valence electrons. For three carbon atoms, that gives us \( 3 \times 4 = 12 \) valence electrons. 2. **Identify Bonds**: In \( C_3O_2 \), we need to consider how the carbon atoms are bonded to each other and to the oxygen atoms. The structure typically involves carbon-carbon and carbon-oxygen bonds. 3. **Calculate Steric Number**: For a carbon atom involved in two sigma bonds and no lone pairs, the steric number is 2, indicating \( sp \) hybridization. ### Step 4: Confirming the Structure Given that each carbon atom is \( sp \) hybridized and the steric number is 2, we can conclude that: - The geometry around each carbon atom is linear, with bond angles of 180 degrees. ### Conclusion Both the assertion that \( C_3O_2 \) has a linear structure and the reason that each carbon atom is \( sp \) hybridized are correct. The reason provided is also a correct explanation of the assertion. ### Final Answer Both the assertion and reason are true, and the reason correctly explains the assertion.
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL BONDING (ADVANCED)

    VK JAISWAL ENGLISH|Exercise SUBJECTIVE PROBLEMS|64 Videos
  • CHEMICAL BONDING (ADVANCED)

    VK JAISWAL ENGLISH|Exercise MATCH THE COLUMN|21 Videos
  • CHEMICAL BONDING (BASIC)

    VK JAISWAL ENGLISH|Exercise SUBJECTIVE PROBLEMS|54 Videos

Similar Questions

Explore conceptually related problems

Number of carbon atom present linearly in C_(3)O_(2) :-

Oxidation number of carbon in carbon suboxide (C_(3)O_(2)) is :

Assertion: - overset(*) (CH_3 ) acts as an electrophile. Reason :-The carbon atom in overset(*)(CH_3) is in a state of sp^2 hybridisation.

Assertion : O_(2) is paramagnetic. Reason : It has one unpaired electron.

Assertion : XeF_(2) is linear Reason :Xe atom in XeF_(2) is sp hybridised

Assertion : C_(3)O_(2) is non-polar molecule. Reason : Terminal pi-bonds of the molecule are lying in different planes.

Assertion : C_(3)O_(2) is non-polar molecule. Reason : Terminal pi-bonds of the molecule are lying in different planes.

The structure of C_3O_2 (Carbon sub-oxide) is

Graphite has a two dimensional sheet-like structure in which each carbon atom is sp^3 hybridized .

Assertion : In gaseous phase, H_(2)O and H_(2)O_(2) both have bent structures. Reason Bond angle of both H_(2)O and H_(2)O_(2) is 104.5^(@) .

VK JAISWAL ENGLISH-CHEMICAL BONDING (ADVANCED)-ASSERTION-REASON TYPE QUESTIONS
  1. Assertion : bond dissociation energy of N-F bond in NF(3) molecule is ...

    Text Solution

    |

  2. Assertion: If d(x^(2)-y^(2)) and p(y) orbitals come close together al...

    Text Solution

    |

  3. Assertion : H(2)S is stronger acid than PH(3). Reason : S is more el...

    Text Solution

    |

  4. Assertion : NaCl is more ionic than NaI. Reason : Chlorine is more e...

    Text Solution

    |

  5. Assertion : PbI(4) doesn't exist and converts into PbI(2) and I(2) spo...

    Text Solution

    |

  6. Assertion : Dipole moment of NF(3) is less than that of NH(3). Reaso...

    Text Solution

    |

  7. Assertion : Solubility of n-orbital of n-orbital in water decrease w...

    Text Solution

    |

  8. Assertion : The unpaired electron of CH(3)^(•) free radical occupies p...

    Text Solution

    |

  9. Assertion : Nitrogen in inactive at room temperature but becomes react...

    Text Solution

    |

  10. Assertion The p - isomer of dichlorobenzene has higher m.p than o-and ...

    Text Solution

    |

  11. Assertion (A): Na(2)SO(4) is soluble in water while BaSO(4) is insolub...

    Text Solution

    |

  12. Assertion : N(2) and NO^(+) both are diamagnetic substances. Reason ...

    Text Solution

    |

  13. Assertion : Bond order can assume any value number including zero. R...

    Text Solution

    |

  14. Assertion: C(3)O(2) has linear structure. Reason: Each carbon atom i...

    Text Solution

    |

  15. Assertion : H-bonding occurs in H(2)O due to larger size of O-atom. ...

    Text Solution

    |

  16. Assertion : (CH(3))(3)N geometry is pyramidal but in case (SiH(3))(3)N...

    Text Solution

    |

  17. Assertion : Supeoxides of alkali matels are paramagnetic. Reason : Su...

    Text Solution

    |

  18. Assertion : The HF(2)^(-) ion exists in the solid state & also in liqu...

    Text Solution

    |

  19. Assertion : If d(x^(2)-y^(2)) and p(y) orbitals come close together al...

    Text Solution

    |

  20. Assertion : The H-bond present in NH(3) dissolved in water is best rep...

    Text Solution

    |