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Assertion : (CH(3))(3)N geometry is pyra...

Assertion : `(CH_(3))_(3)N` geometry is pyramidal but in case `(SiH_(3))_(3)N` it is planar.
Reason :The maximum covalency of Si is six but that of C is four.

A

If assertion is true but the reason is false

B

If assertion is false but reason is true

C

If both assertion and reason are true and the reason is the correct explanation of assertion

D

If both assertion and reason are true and the reason is not the correct explanation of assertion

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided in the statement. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that the geometry of `(CH₃)₃N` (trimethylamine) is pyramidal, while the geometry of `(SiH₃)₃N` (trihydrosilazane) is planar. - To analyze this, we need to consider the hybridization and molecular geometry of both compounds. 2. **Analyzing `(CH₃)₃N`**: - In trimethylamine, the nitrogen atom is bonded to three methyl groups (CH₃) and has a lone pair of electrons. - The presence of the lone pair causes the geometry to be trigonal pyramidal due to the repulsion between the lone pair and the bonding pairs (VSEPR theory). 3. **Analyzing `(SiH₃)₃N`**: - In trihydrosilazane, silicon is bonded to three hydrogen atoms and one nitrogen atom. - Silicon can utilize its d-orbitals to form bonds, allowing it to accommodate more than four bonds. - The geometry of `(SiH₃)₃N` is planar because the bonding involves sp² hybridization, resulting in a trigonal planar arrangement. 4. **Understanding the Reason**: - The reason states that the maximum covalency of silicon is six, while that of carbon is four. - This is true because silicon can expand its octet by utilizing its d-orbitals, whereas carbon cannot because it lacks d-orbitals. 5. **Conclusion**: - Both the assertion and the reason are true. - However, the reason does not correctly explain the assertion. The assertion about the geometries is primarily due to the presence of a lone pair in nitrogen for `(CH₃)₃N`, while silicon's ability to form a planar structure is due to its capacity to utilize d-orbitals. ### Final Answer: Both the assertion and the reason are true, but the reason is not the correct explanation of the assertion. ---

To solve the question, we need to analyze both the assertion and the reason provided in the statement. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that the geometry of `(CH₃)₃N` (trimethylamine) is pyramidal, while the geometry of `(SiH₃)₃N` (trihydrosilazane) is planar. - To analyze this, we need to consider the hybridization and molecular geometry of both compounds. ...
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