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Select the correct code about complex [C...

Select the correct code about complex `[Cr(NO_(2))(NH_(3))_(5)][ZnCl_(4)]`:
(I) IUPAC anem of compound is pentaamminenitrito-N-chromium (III) tetrachlorozincate (II)
(II) it shows geometrical isomerism
(III) It shows linkage isomerism
(IV) it shows coordination isomerism

A

III, IV

B

I, III, IV

C

II, III and IV

D

I, II, III and IV

Text Solution

Verified by Experts

The correct Answer is:
B
(I) IUPAC name is Pentaamminetrito-N-chromium(III) tetrachlorozincate
(II) It does not exhibit geometrical isomerism.
(III) it show linkage isomerism due to presence of ambidentate ligand `NO_(2)^(-)`
(IV) its coordination isomers are:
`[CrCl(NH_(3))_(5)][ZnCl_(3)(NO_(2))],[CrCl_(2)(NH_(3))_(4)][ZnCl_(2)(NO_(2))NH_(3)]`
`[Zn(NO_(2))(NH_(3))_(3)][CrCl_(4)(NH_(3))_(2)]`
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Select the correct code about complex [Cr(NO_(2))(NH_(3))_(5)][ZnCl_(4)] : (I) IUPAC name of compoun is pentaamminenitrito -N- chromium (III) tetrachlorozincate (II) (II) It shows geometrical isomerism (III) It shows linkage isomerism (IV) It shows coordination isomerism

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VK JAISWAL ENGLISH-CO-ORDINATION COMPOUNDS-LEVEL 2
  1. Select the correct code about complex [Cr(NO(2))(NH(3))(5)][ZnCl(4)]: ...

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  2. Which of the following ligand does not as pi-acid ligand?

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  3. If EAN of central metal cation M^(2+) in an non-chelating complex is 3...

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  4. [Mn(CO)(4)NO] is diamagnetic because:

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  5. Choose the correct option regarding the following complex compound whi...

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  6. If CO ligands are substituted by NO in respective neutral carbonyl com...

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  7. Which of the following species can act as reducing agent ?

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  8. If Delta(0) lt P, the correct electronic configuration for d^(4) syste...

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  9. Which of the following statement is not correct?

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  10. Give the correct of initials T or F for following statements. Use T if...

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  11. match List-I with list-II and select the correct answer using the code...

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  12. The value of 'spin only' magnetic moment for one of the following conf...

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  13. The correct order of magnetic moments (spin values in B.M.) among is:

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  14. Which of the following statements is incorrect?

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  15. Set of d-orbitals which is used by central metal during formation of M...

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  16. FeSO(4) is a very good absorber for NO, the new compound formed by thi...

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  17. A [M(H(2)O)(6)]^(2+) complex typically absorbs at around 600 n. it is ...

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  18. Given that the energy of the photons of different colours decreases in...

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  19. The CFSE for octahedral [CoCl(6)]^(4-) is 18,000 cm^(-1) . The CFSE fo...

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  20. MnO(4)^(-) is of intense pink colour, though Mn is in(+7) oxidation st...

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  21. In which of the following complex ion the value of magnetic moment (sp...

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