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MnO(4)^(-) is of intense pink colour, th...

`MnO_(4)^(-)` is of intense pink colour, though Mn is in (+7) oxidation state, it is due to:

A

oxygen gives colour to it

B

Charge transfer when Mn(+7) gives its electron to oxygen and oxidise to Mn (+8) temporarily

C

Charge transfer when oxygen gives its electron to Mn(+7) changing in Mn(+6)

D

none is correct explanation

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The correct Answer is:
C
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Transition metals usually from coloured complexes and d-d transitions (t_(2g)hArre_(g)) are responsible for colour as the energy difference between t_(2g) and e_(g) lies in visible region. But all the coloured ions are not dut to d-d transition but charge transfer bands also play important roles. Charge transfer bands may be of two types. (i) ligand to metal (CTLM) " "(ii) metal to ligand (CTML). Charge transfer transition always produces intense colour as compared to d-d transition. MnO_(4)^(-) is dark purple coloured though Mn is in (+VII) oxidation state with 3d^(@) configuration

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Assertion : Solution of Na_(2) CrO_(4) in water is intensely coloured Reason : Oxidation state of Cr in Na_(2) CrO_(4) is + VI .

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VK JAISWAL ENGLISH-CO-ORDINATION COMPOUNDS-LEVEL 2
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  4. In which of the following complex ion the value of magnetic moment (sp...

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  5. Which of the following order of CFSE is incorrect?

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  6. For which of the following d^(n) configuration of octahedral complex(e...

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  8. The pi acid ligand which uses it d-orbital during synergic bonding in ...

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  9. The IR stretching frequencies of free CO, and CO in [V(CO)(6)]^(-),[C...

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  10. The pi acid ligand which uses it d-orbital during synergic bonding in ...

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  13. In which of the following ion the value of magentic moment (spin only)...

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  14. The inner orbital complex which exhibits both geometrical as well as o...

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  15. Select correct statement(s) regarding [Ni(DMG)(2)] complex compound:

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  19. Which of the following is correct matched?

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