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Select the correct code regarding total ...

Select the correct code regarding total number of space isomers for the following compounds:
(I) `[Ma_(3)b_(2)c]^(n+-)`
(II) `[M(AB)_(3)]^(n+-)`
(III) `[Ma_(2)b_(2)c_(2)]^(n+-)`

A

(I)-4,(II)-4,(III)-6

B

(I)-4,(II)-3,(III)-5

C

(I)-3,(II)-3,(III)-5

D

(I)-3,(II)-4,(III)-6

Text Solution

AI Generated Solution

The correct Answer is:
To determine the total number of space isomers for the given coordination compounds, we will analyze each compound step by step. ### Step 1: Analyze Compound I - `[Ma_(3)b_(2)c]^(n+-)` 1. **Identify the Ligands**: The compound has three 'A' ligands, two 'B' ligands, and one 'C' ligand. 2. **Cis and Trans Isomers**: - **Cis Isomer**: The 'A' ligands can be positioned adjacent to each other. This gives us one distinct cis configuration. - **Trans Isomers**: The 'A' ligands can also be positioned opposite to each other. We can have two distinct trans configurations: - One with 'A' ligands on one side and 'B' ligands on the other. - Another with 'A' ligands on opposite sides. 3. **Total Isomers**: - 1 (cis) + 2 (trans) = 3 total isomers. 4. **Optical Activity**: All isomers are optically inactive. ### Step 2: Analyze Compound II - `[M(AB)_(3)]^(n+-)` 1. **Identify the Ligands**: The compound has three bidentate ligands 'AB'. 2. **Cis and Trans Isomers**: - **Cis Isomers**: There is one distinct configuration where the 'AB' ligands are adjacent. - **Trans Isomers**: There are two distinct configurations where the 'AB' ligands are opposite each other. 3. **Total Isomers**: - 1 (cis) + 2 (trans) = 3 total isomers. 4. **Optical Activity**: Both configurations are optically active. ### Step 3: Analyze Compound III - `[Ma_(2)b_(2)c_(2)]^(n+-)` 1. **Identify the Ligands**: The compound has two 'A' ligands, two 'B' ligands, and two 'C' ligands. 2. **Cis and Trans Isomers**: - **Cis Isomers**: There is one distinct configuration where two 'A' ligands are adjacent, and the same for 'B' and 'C'. - **Trans Isomers**: There are four distinct configurations where 'A', 'B', and 'C' ligands are positioned opposite each other. 3. **Total Isomers**: - 1 (cis) + 4 (trans) = 5 total isomers. 4. **Optical Activity**: The cis isomer is optically active, while the trans isomers are optically inactive. ### Summary of Total Space Isomers - **Compound I**: 3 isomers - **Compound II**: 4 isomers - **Compound III**: 6 isomers ### Final Answer The correct code regarding the total number of space isomers is: - Compound I: 3 - Compound II: 4 - Compound III: 6 Thus, the answer is **3, 4, 6**.

To determine the total number of space isomers for the given coordination compounds, we will analyze each compound step by step. ### Step 1: Analyze Compound I - `[Ma_(3)b_(2)c]^(n+-)` 1. **Identify the Ligands**: The compound has three 'A' ligands, two 'B' ligands, and one 'C' ligand. 2. **Cis and Trans Isomers**: - **Cis Isomer**: The 'A' ligands can be positioned adjacent to each other. This gives us one distinct cis configuration. - **Trans Isomers**: The 'A' ligands can also be positioned opposite to each other. We can have two distinct trans configurations: ...
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VK JAISWAL ENGLISH-CO-ORDINATION COMPOUNDS-LEVEL 2
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