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Complex compounds that have the same molecular formula but have different structural/space arrangements of ligands around central metal atom/ion are called isomers, these are of two types namely structural and stereoisomers.
Q. Which of the following is different among structural isomers?

A

Oxidation state

B

Co-ordination number

C

IUPAC name

D

None of these

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The correct Answer is:
To solve the question regarding the differences among structural isomers, we can follow these steps: ### Step 1: Understand the concept of isomers Isomers are compounds that have the same molecular formula but different structural or spatial arrangements of atoms. They can be classified into two main types: structural isomers and stereoisomers. **Hint:** Remember that structural isomers differ in how their atoms are connected, while stereoisomers differ in the spatial arrangement of their atoms. ### Step 2: Identify the types of structural isomers Structural isomers can be further divided into several categories, including: - Chain isomerism - Position isomerism - Functional group isomerism - Linkage isomerism **Hint:** Think about how the arrangement of ligands or functional groups can lead to different structural forms. ### Step 3: Analyze the options given in the question The question provides four options regarding what could be different among structural isomers: 1. Oxidation state 2. Coordination number 3. IUPAC name 4. None of these **Hint:** Consider how each of these properties might change or remain the same when comparing structural isomers. ### Step 4: Evaluate each option - **Oxidation state:** In structural isomers, the oxidation state of the central metal ion often remains the same. For example, if you have a metal ion with a certain oxidation state in one isomer, it will typically have the same oxidation state in its structural isomer. - **Coordination number:** The coordination number, which is the number of ligands attached to the central metal ion, also remains the same among structural isomers. For instance, if a complex has six ligands in one isomer, it will have six in all structural isomers. - **IUPAC name:** The IUPAC name of structural isomers will differ due to the different arrangements of ligands. For example, if one isomer has a thiocyanate ligand (SCN) and another has an isothiocyanate ligand (NCS), their IUPAC names will reflect this difference. - **None of these:** This option implies that none of the previous options differ, which is not correct since we have established that the IUPAC names differ. **Hint:** Focus on the unique naming conventions in chemistry that ensure each compound has a distinct name based on its structure. ### Step 5: Conclusion Based on the analysis, the correct answer is that the **IUPAC name** is different among structural isomers. ### Final Answer **IUPAC name**
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