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Recent X-ray work, IR and other spectros...

Recent X-ray work, IR and other spectroscopic methods have proved that Turnbull's blue is identical to Prussian blue.
Q. What is the common formula of Turnbull's blue and Prussian blue?

A

`Fe_(3)[Fe(CN)_(6)]_(2)`

B

`Fe_(4)[Fe(CN)_(6)]_(3)`

C

`KF e[Fe(CN)_(6)]`

D

`KF e_(2)[Fe(CN)_(6)]`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the common formula of Turnbull's blue and Prussian blue, we can follow these steps: ### Step 1: Identify the compounds Turnbull's blue and Prussian blue are both known as dark blue pigments. They are used in various applications, including paints and blueprints. ### Step 2: Understand the chemical composition Prussian blue is also known as ferric ferrocyanide, and its chemical formula is often represented as \( \text{Fe}_3[\text{Fe(CN)}_6]_2 \). Turnbull's blue is similar in structure and is known as ferrous ferrocyanide, with the formula \( \text{Fe}_3[\text{Fe(CN)}_6]_2 \) as well. ### Step 3: Write the common formula Both Turnbull's blue and Prussian blue can be represented by the formula \( \text{Fe}_3[\text{Fe(CN)}_6]_2 \) or \( \text{Fe}_4[\text{Fe(CN)}_6]_3 \) when considering the overall stoichiometry. However, the most commonly accepted formula for both is \( \text{Fe}_3[\text{Fe(CN)}_6]_2 \). ### Conclusion The common formula of Turnbull's blue and Prussian blue is \( \text{Fe}_3[\text{Fe(CN)}_6]_2 \). ---
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