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Consider the following two reactions: ...

Consider the following two reactions:
`Cd^(2+)(aq.)+4CH_(3)NH_(2) overset(K_(1)) to 'A',DeltaG_(1)^(@)`
`Cd^(2+)(aq.)+2H_(2)NCH_(2)CH_(2)NH_(2) overset(K_(2)) to 'B',DeltaG_(2)^(@)`. According to given information the correct statement(s) is/are:

A

`DeltaG_(2)^(@)` is more negative than `DeltaG_(1)^(@)`

B

Compound 'A" is optically inactive

C

Compound 'B' is optically active

D

Formation constant `K_(2)` is greater than formation constant `K_(1)`

Text Solution

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The correct Answer is:
A, B, D
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VK JAISWAL ENGLISH-CO-ORDINATION COMPOUNDS-ONE OR MORE ANSWERS IS/ARE CORRECT
  1. Which of the following statement(s) is(are) correct?

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  2. Which is/are correct statement(s)?

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  3. Consider the following two reactions: Cd^(2+)(aq.)+4CH(3)NH(2) overs...

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  4. Complex compound [Co(SCN)(2)(NH(3))(4)]Cl exhibits:

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  5. Which of the following compound has/have effective atomic number equal...

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  6. Select correct statement(s) regarding octahedron complex having CFSE=-...

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  7. Consider the following two carbonyl compounds (i) [Tc(CO)(6)]^(+) an...

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  8. Which of the following ligand does not as pi-acid ligand?

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  9. Find out correct IUPAC name of complex compound

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  10. Consider the following reactions of complex compounds A,B and C (i) ...

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  11. Which complex species does/do not exhibit geometrical and only have tw...

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  12. Which of the following complex(s) can not exhibit both geometrical and...

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  13. Complex ions [NiCl(6)]^(4-),[Ni(CN)(6)]^(4-) similar in their given pr...

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  14. Select correct statement(s) regarding given complexes:

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  15. Complex compound [Co(SCN)(2)(NH(3))(4)]Cl exhibits:

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  16. Which of the following compound has/have effective atomic number equal...

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  17. K(2)[Ni(CN)(4)] underset(NH(3))overset("K in liq.")to"X' Regarding t...

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  18. Which of the following statement(s) is/are correct?

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  19. Which one of the following statement(s) is/are false?

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  20. A d-block element forms octahedral complex but its magnetic moment rem...

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