Home
Class 12
CHEMISTRY
Consider the following reactions of comp...

Consider the following reactions of complex compounds A,B and C
(i) `ClCl_(2)Br*5NH_(3) +excess" "Ag^(+)(aq)to1AgCl(s)`
(ii) `underset("Compound B")(CoCl_(2)Br*5NH_(3))+"excess "Ag^(+)(aq) to 2AgCl(s)`
(iii) `underset("Compound C")(CoCl_(2)Br*4NH_3)+"excess "Ag^(+)(aq.) to 1AgCl(s)`
Then according to the given information the correct statement(s) is/are:

A

Compounds(A) and (B) are ionisation isomers

B

Molar conductivity of compounds (A) and (B) are almost same

C

Compounds (A), (B) and (C) do not exhibit geometrical isomerism

D

Order of CFSE values, `Delta_(0)(A) gt Delta_(0)(B) gt Delta_(0)(C)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem regarding the complex compounds A, B, and C, we will analyze the reactions and the properties of these compounds step by step. ### Step 1: Identify the Complex Compounds From the reactions provided: 1. **Compound A**: \( \text{[CoCl}_2\text{Br(NH}_3)_5] \) 2. **Compound B**: \( \text{[CoCl}_2\text{Br(NH}_3)_5] \) 3. **Compound C**: \( \text{[CoCl}_2\text{Br(NH}_3)_4] \) ### Step 2: Analyze the Reactions 1. **For Compound A**: \[ \text{[CoCl}_2\text{Br(NH}_3)_5] + \text{excess } \text{Ag}^+ \text{(aq)} \rightarrow 1 \text{AgCl}(s) \] This indicates that one chloride ion is released. 2. **For Compound B**: \[ \text{[CoCl}_2\text{Br(NH}_3)_5] + \text{excess } \text{Ag}^+ \text{(aq)} \rightarrow 2 \text{AgCl}(s) \] This indicates that two chloride ions are released. 3. **For Compound C**: \[ \text{[CoCl}_2\text{Br(NH}_3)_4] + \text{excess } \text{Ag}^+ \text{(aq)} \rightarrow 1 \text{AgCl}(s) \] This indicates that one chloride ion is released. ### Step 3: Determine Ionization Isomers - **Compounds A and B**: Both contain the same ligands but differ in the arrangement of bromide and chloride ions. They are ionization isomers because they can produce different ions upon dissociation. - **Compound C**: It has one less ammonia ligand compared to A and B, which may affect its ionization properties. ### Step 4: Molar Conductivity - **Molar Conductivity of A and B**: Since both compounds yield the same number of ions upon dissociation (3 ions), their molar conductivities will be similar. - **Compound C**: It will yield fewer ions compared to A and B, leading to lower molar conductivity. ### Step 5: Geometrical Isomers - **Compounds A and B**: They do not exhibit geometrical isomerism because they have five identical ligands (ammonia). - **Compound C**: It can exhibit geometrical isomerism due to the presence of different ligands (bromide and chloride) and fewer identical ligands. ### Step 6: Crystal Field Stabilization Energy (CFSE) - The CFSE depends on the nature of the ligands. Strong field ligands (like NH3) will stabilize the complex more than weak field ligands (like Br and Cl). - **Order of CFSE**: A (with 5 NH3) > B (with 5 NH3 and 2 Cl) > C (with 4 NH3 and 1 Cl). ### Conclusion Based on the analysis, we can summarize the statements: 1. **A and B are ionization isomers**: True 2. **Molar conductivities of A and B are almost the same**: True 3. **Compounds A, B, C do not exhibit geometrical isomers**: False (C can exhibit geometrical isomers) 4. **Order of CFSE is A > B > C**: True ### Final Statements The correct statements are: - A and B are ionization isomers. - Molar conductivities of A and B are almost the same. - The order of CFSE is A > B > C.

To solve the problem regarding the complex compounds A, B, and C, we will analyze the reactions and the properties of these compounds step by step. ### Step 1: Identify the Complex Compounds From the reactions provided: 1. **Compound A**: \( \text{[CoCl}_2\text{Br(NH}_3)_5] \) 2. **Compound B**: \( \text{[CoCl}_2\text{Br(NH}_3)_5] \) 3. **Compound C**: \( \text{[CoCl}_2\text{Br(NH}_3)_4] \) ...
Promotional Banner

Topper's Solved these Questions

  • CO-ORDINATION COMPOUNDS

    VK JAISWAL ENGLISH|Exercise MATCH THE COLUMN|36 Videos
  • CO-ORDINATION COMPOUNDS

    VK JAISWAL ENGLISH|Exercise ASSERTION-REASON TYPE QUESTIONS|26 Videos
  • CO-ORDINATION COMPOUNDS

    VK JAISWAL ENGLISH|Exercise LEVEL 3 (PASSAGE TYPE)|98 Videos
  • CHEMICAL BONDING (BASIC)

    VK JAISWAL ENGLISH|Exercise SUBJECTIVE PROBLEMS|54 Videos
  • d-BLOCK ELEMENTS

    VK JAISWAL ENGLISH|Exercise ASSERTION-REASON TYPE QUESTIONS|32 Videos

Similar Questions

Explore conceptually related problems

Which of the following is correct for both the following coordination compounds ? (I) CoCl_(3).6NH_(3) and " " (II) PtCl_(4).5NH_(3)

Consider the following reactions, A_(x)+yB_(2) underset("supply of air")overset("limited")to"Compound"'P' underset("excess air")overset(+zB_(2))to Compound 'Q' If atomic number of elements A and B are 15 and 8 respectively, then according to the given information the correct statement(s) is/are:

Which of the following is correct order of basic strength for the given compounds ? (i) CH_(3)-underset(NH)underset(||)(CH_(3)-C-NH_(2))" "(ii) underset(NH)underset(||)(CH_(3)-C-CH_(3))

Complete and balance the following reaction. (i) Na_(2)S + CdCO_(3) to …..+…. , (ii) CoCl_(2)+NH_(2)SCN overset("Ether")to ….+….

Complete the following reactions: (a) underset("(Equal volume)")(Cl_2+F_2)overset(473 K) to , (b) I_2+ underset("(Excess)")(3Cl_2)to (c ) Br_2+3F_2to (d) Br_2+ underset("(Excess)")(5F_2 )to

For the following reaction Ag_2SO_4(s) ⇋ 2Ag^+ (aq) + SO_4^(2-) (aq) More SO_4^(2-) can be produced by

Complete the following reactions: 2Me_(3)C--Br overset (Ag_(2)CO_(3)) underset (Delta) rarr (A)

Assertion : Aqueous solution of the compound CoCl_(3) * 4NH_(3) when treated with excess of AgNO_3 , 1 mole of AgCl is precipitated . Reason : The compound CoCl_(3) * 4NH_(3) has six primary valencies and one secondary valency .

R-NH_(2)+underset("excess")(CH_(3)COCl)toA . The product (A) Will be

Which of the following isomerism is/are shown by the complex [CoCl_(2)(H_(2)O)_(2)(NH_(3))_(2)] Br ?

VK JAISWAL ENGLISH-CO-ORDINATION COMPOUNDS-ONE OR MORE ANSWERS IS/ARE CORRECT
  1. Which of the following ligand does not as pi-acid ligand?

    Text Solution

    |

  2. Find out correct IUPAC name of complex compound

    Text Solution

    |

  3. Consider the following reactions of complex compounds A,B and C (i) ...

    Text Solution

    |

  4. Which complex species does/do not exhibit geometrical and only have tw...

    Text Solution

    |

  5. Which of the following complex(s) can not exhibit both geometrical and...

    Text Solution

    |

  6. Complex ions [NiCl(6)]^(4-),[Ni(CN)(6)]^(4-) similar in their given pr...

    Text Solution

    |

  7. Select correct statement(s) regarding given complexes:

    Text Solution

    |

  8. Complex compound [Co(SCN)(2)(NH(3))(4)]Cl exhibits:

    Text Solution

    |

  9. Which of the following compound has/have effective atomic number equal...

    Text Solution

    |

  10. K(2)[Ni(CN)(4)] underset(NH(3))overset("K in liq.")to"X' Regarding t...

    Text Solution

    |

  11. Which of the following statement(s) is/are correct?

    Text Solution

    |

  12. Which one of the following statement(s) is/are false?

    Text Solution

    |

  13. A d-block element forms octahedral complex but its magnetic moment rem...

    Text Solution

    |

  14. For which of the followng d^(n) configuration complexes, can not exist...

    Text Solution

    |

  15. Which of the following pairs show coordination isomerism?

    Text Solution

    |

  16. Which of the following are coordination isomers of [Co(NH(3))(6)][Cr(C...

    Text Solution

    |

  17. Which of the following statements is not true about the complex ion [C...

    Text Solution

    |

  18. Which of the following statement(s) is/are incorrect?

    Text Solution

    |

  19. Which of the following statement is true about the complex [CrCl(3)(OH...

    Text Solution

    |

  20. Which of the following is correct about Tetraamminedithiocyanato-s cob...

    Text Solution

    |