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AgNO(3) overset(Delta)(to)(W)+(X)+O(2) ...

`AgNO_(3) overset(Delta)(to)(W)+(X)+O_(2)`
`(X)+H_(2)O to HNO_(2)+HNO_(3)`
`(W)+HNO_(3) to Y+NO+H_(2)O`
`(Y)+Na_(2)S_(2)O_(3)("excess") to (Z)+NaNO_(3)`
Identify (W) to (Z).

A

`W=Ag, X=N_(2)O,Y=AgNO_(3),Z=Na_(2)[Ag(S_(2)O_(3))_(2)]`

B

`W=Ag_(2)O, X=NO,Y=AgNO_(3),Z=Na_(3)[Ag(S_(2)O_(3))_(2)]`

C

`W=Ag, X=NO_(2),Y=AgNO_(3),Z=Na_(3)[Ag(S_(2)O_(3))_(2)]`

D

`W=Ag_(2)O, X=N_(2),Y=AgNO_(3),Z=Na[Ag(S_(2)O_(3))_(2)]`

Text Solution

Verified by Experts

The correct Answer is:
C

`Na_(2)[overset(II)(Fe)(NO)(CN)_(5)]+Na_(2)S to Na[overset(II)(Fe)(CN)_(5)(NOS)]`
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AgNO_(3)overset(Delta)(rarr)(W)+(X)+O_(2) (X)+H_(2)OrarrHNO_(2)+HNO_(3) (W)+HNO_(3)rarrY+NO+H_(2)O (Y)+Na_(2)S_(2)O_(3)("excess")rarr(Z)+NaNO_(3)

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NaNO_(3) overset(Delta) to NaNO_(2)+O_(2)

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