Home
Class 12
CHEMISTRY
Transition metal and their compounds are...

Transition metal and their compounds are used as catalyst in industry and in biological system. For example, in the Contact Process, vanadium compounds in the +5 state `(V_(2)O_(5) or VO_(3)^(-))` are used to oxidise `SO_(2)` to `SO_(3)`:
`SO_(2)+(1)/(2)O_(2) overset(V_(2)O_(5))(to) SO_(3)`
It is thought thta the actual oxidation process takes place in two stages. In the first step, `V^(5+)` in the presence of oxide ions converts `SO_(2)` to `SO_(3)`. At the same time, `V^(5+)` is reduced to `V^(4+)`.
`2V^(5+)+O^(2-)+SO_(2) to 2V^(4+)+SO_(3)`
In the second step, `V^(5+)` is regenerated from `V^(4+)` by oxygen:
`2V^(4+)+(1)/(2)O_(2) to 2V^(5+)+O^(2-)`
The overall process is, of curse, the sum of these two steps:
`SO_(2) +(1)/(2)O_(2) to SO_(3)`
Q. Catalytic activity in transition metals depends on:

A

Their ability to exist in different oxidation states

B

The size of the metal atoms

C

The number of empty atomic orbitals available

D

None of these

Text Solution

Verified by Experts

The correct Answer is:
A
Promotional Banner

Topper's Solved these Questions

  • d-BLOCK ELEMENTS

    VK JAISWAL ENGLISH|Exercise ONE OR MORE ANSWER IS/ARE CORRECT|44 Videos
  • d-BLOCK ELEMENTS

    VK JAISWAL ENGLISH|Exercise MATCH THE COLUMN|3 Videos
  • d-BLOCK ELEMENTS

    VK JAISWAL ENGLISH|Exercise ASSERTION-REASON TYPE QUESTIONS|32 Videos
  • CO-ORDINATION COMPOUNDS

    VK JAISWAL ENGLISH|Exercise LEVEL 2|144 Videos
  • ENVIRONMENTAL CHEMISTRY

    VK JAISWAL ENGLISH|Exercise ASSERTION-REASON TYPE QUESTIONS|14 Videos

Similar Questions

Explore conceptually related problems

Transition metal and their compounds are used as catalyst in industry and in biological system. For example, in the Contact Process, vanadium compounds in the +5 state (V_(2)O_(5) or VO_(3)^(-)) are used to oxidise SO_(2) to SO_(3) : SO_(2)+(1)/(2)O_(2) overset(V_(2)O_(5))(to) SO_(3) It is thought thta the actual oxidation process takes place in two stages. In the first step, V^(5+) in the presence of oxide ions converts SO_(2) to SO_(3) . At the same time, V^(5+) is reduced to V^(4+) . 2V^(5+)+O^(2-)+SO_(2) to 2V^(4+)+SO_(3) In the second step, V^(5+) is regenerated from V^(4+) by oxygen: 2V^(4+)+(1)/(2)O_(2) to 2V^(5+)+O^(2-) The overall process is, of curse, the sum of these two steps: SO_(2) +(1)/(2)O_(2) to SO_(3) Q. During the course of the reaction:

Sulphate salt metal oxide and SO_(3)(or SO_(2)+(1)/(2)O_(2)) on heating:

Sulphate salt gives metal oxide and SO_(3)(or SO_(2)+(1)/(2)O_(2)) on heating:

The oxidation of benzene by V_(2)O_(5) in the presence of aire produces

The oxidation of benzene by V_(2)O_(5) in the presence of aire produces

The oxidation of benzene by V_(2)O_(5) in the presence of aire produces

In the reaction, H_(2)SO_(4)+P_(2)O_(5)overset(Delta)to (X)+SO_(3) , the product (X) is :

In the contact process of manufacturing of H_(2) SO_(4) the catalyst used is

Among the following, the number of compounds that can react with PCl_(5) to give POCl_(3) is O_(2) , CO_(2) , SO_(2) , H_(2)O , H_(2)SO_(4) , P_(4)O_(10) .

Sulphur has highest oxidation state in a. SO_(2) b. H_(2)SO_(4) c. Na_(2)S_(4)O_(6) d. Na_(2)S_(2)O_(3)

VK JAISWAL ENGLISH-d-BLOCK ELEMENTS-Level 3
  1. Iron forms iron halides salts by reacting the metal directly with halo...

    Text Solution

    |

  2. Iron forms iron halides salts by reacting the metal directly with halo...

    Text Solution

    |

  3. In salts of polyatomic anion, as polarising power of cation increase, ...

    Text Solution

    |

  4. In salts of polyatomic anion, as polarising power of cation increase, ...

    Text Solution

    |

  5. Light green (compound 'A')overset(Delta)(to)"white Residue(B)"overset(...

    Text Solution

    |

  6. Light green (compound 'A')overset(Delta)(to)"white Residue(B)"overset(...

    Text Solution

    |

  7. Light green (compound 'A')overset(Delta)(to)"white Residue(B)"overset(...

    Text Solution

    |

  8. Light green (compound 'A')overset(Delta)(to)"white Residue(B)"overset(...

    Text Solution

    |

  9. Transition metal and their compounds are used as catalyst in industry ...

    Text Solution

    |

  10. Transition metal and their compounds are used as catalyst in industry ...

    Text Solution

    |

  11. MnO(2) is the most important oxide of manganese , MnO(2) occurs natual...

    Text Solution

    |

  12. MnO(2) is the most important oxide of manganese , MnO(2) occurs natual...

    Text Solution

    |

  13. MnO(2) is the most important oxide of manganese , MnO(2) occurs natual...

    Text Solution

    |

  14. MnO(2) is the most important oxide of manganese , MnO(2) occurs natual...

    Text Solution

    |

  15. Iron (+II) is one of the most important oxidation states and salts are...

    Text Solution

    |

  16. Iron (+II) is one of the most important oxidation states and salts are...

    Text Solution

    |

  17. Iron (+II) is one of the most important oxidation states and salts are...

    Text Solution

    |

  18. Iron forms iron halides salts by reacting the metal directly with halo...

    Text Solution

    |

  19. Iron forms iron halides salts by reacting the metal directly with halo...

    Text Solution

    |

  20. Iron forms iron halides salts by reacting the metal directly with halo...

    Text Solution

    |