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I(2)+S(2)O(3)^(2-) to I^(-)+S(4)O(6)^(2-...

`I_(2)+S_(2)O_(3)^(2-) to I^(-)+S_(4)O_(6)^(2-)`

A

For disproportionation reaction.

B

For comproportionation reaction.

C

For either intermolecular redox reaction or displacement reaction

D

For either thermal combination redox reaction or thermal decomposition redox reaction.

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The correct Answer is:
To determine the type of reaction represented by the equation \( I_2 + S_2O_3^{2-} \rightarrow I^{-} + S_4O_6^{2-} \), we will follow these steps: ### Step 1: Identify the oxidation states of each element in the reaction. 1. **For \( I_2 \)**: The oxidation state of iodine in its elemental form is 0. 2. **For \( I^{-} \)**: The oxidation state of iodine is -1. 3. **For \( S_2O_3^{2-} \)**: Let the oxidation state of sulfur be \( X \). The equation becomes: \[ 2X + 3(-2) = -2 \implies 2X - 6 = -2 \implies 2X = 4 \implies X = +2 \] So, sulfur in \( S_2O_3^{2-} \) has an oxidation state of +2. 4. **For \( S_4O_6^{2-} \)**: Let the oxidation state of sulfur be \( Y \). The equation becomes: \[ 4Y + 6(-2) = -2 \implies 4Y - 12 = -2 \implies 4Y = 10 \implies Y = 2.5 \] Thus, sulfur in \( S_4O_6^{2-} \) has an oxidation state of +2.5. ### Step 2: Analyze the changes in oxidation states. - **Iodine**: Changes from 0 (in \( I_2 \)) to -1 (in \( I^{-} \)). This indicates a reduction (gain of electrons). - **Sulfur**: Changes from +2 (in \( S_2O_3^{2-} \)) to +2.5 (in \( S_4O_6^{2-} \)). This indicates an oxidation (loss of electrons). ### Step 3: Classify the reaction. Since one species (iodine) is being reduced while another species (sulfur) is being oxidized, this reaction is classified as a **redox reaction**. Specifically, because two different reactant molecules are involved, it is an **intermolecular redox reaction**. ### Conclusion The type of reaction represented by the equation \( I_2 + S_2O_3^{2-} \rightarrow I^{-} + S_4O_6^{2-} \) is an **intermolecular redox reaction**. ---
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In the reaction, I_(2)+2S_(2)O_(3)^(2-) rarr 2I^(-)+S_(4)O_(6)^(2-) .

In the reaction, I_(2)+2S_(2)O_(3)^(2-) rarr 2I^(-)+S_(4)O_(6)^(2-) . Equivalent wieght of iodine will be equal to

In the reaction, I_(2)+2S_(2)O_(3)^(2-) rarr 2I^(-)+S_(4)O_(6)^(2-) . Equivalent wieght of iodine will be equal to

A constant current was flowen for 1 mi n through a solution of Kl . At the end of experiment, liberated I_(2) consumed 150mL of 0.01M solution of Na_(2)S_(2)O_(3) following the reaction : I_(2)+2S_(2)O_(3)^(2-) rarr 2I^(c-)+S_(4)O_(6)^(2-) What was the average rate of current flow in ampere ?

Three different solutions of oxidising agents KMnO_(4),K_(2)Cr_(2)O_(7) " and "I_(2) is titrated separately with 0.158 gm of Na_(2)S_(2)O_(3) . If molarity of each oxidising agent is 0.1 M and reactions are : I. MnO_(4)^(-)+S_(2)O_(3)^(2-) toMnO_(2)+SO_(4)^(2-) II CrO_(7)^(2-)+S_(2)O_(3)^(2-) to Cr^(3+)+SO_(4)^(2-) III. I_(2)+S_(2)O_(3)^(2-) to S_(4)O_(6)^(2-)+I^(-)

The reaction S_(2)O_(8)^(2-) + 3I^(ɵ) rarr 2SO_(4)^(2-) + I_(3)^(ɵ) is of first order both with respect to persulphate and iofide ions. Taking the initial concentration as a and b , respectively, and taking x as the concentration of the triofide at time t , a differential rate equation can be written. Two suggested mechanism for the reaction are: I. S_(2)O_(8)^(2-)+I^(ɵ) hArr SO_(4)I^(ɵ)+SO_(4)^(2-) ("fast") I^(ɵ)+SO_(4)I^(ɵ) overset(k_(1))rarrI_(2) + SO_(4)^(2-) (show) I^(ɵ) + I_(2) overset(k_(2))rarr I_(3)^(ɵ) ("fast") II. S_(2)O_(8)^(2-) + I^(ɵ) overset(k_(1))rarr S_(2)O_(8) I^(2-) (slow) S_(2)O_(8)I^(3-) overset(k_(2))rarr2SO_(4)^(2-)+I^(o+) ("fast") I^(o+) + I^(ɵ) overset(k_(3)) rarr I_(2) ("fast") I_(2) + I^(o+) overset(k_(4))rarr I_(3)^(ɵ) ("fast") For the reaction I_(2)+2S_(2)O_(3)^(2-) rarr S_(4)O_(6)^(2-) + 2I^(ɵ) I. (-d[I_(2)])/(dt) = -(1)/(2) (d[S_(2)O_(3)^(2-)])/(dt) II. (-d[I_(2)])/(dt) = -2 (d[S_(2)O_(3)^(2-)])/(dt) III. (-d[I_(2)])/(dt) = -2 (d[I^(ɵ)])/(dt) xx (d[S_(2)O_(3)^(2-)])/(dt) IV. (d[S_(4)O_(6)^(2-)])/(dt) = (1)/(2)(d[I^(ɵ)])/(dt) The correct option is

In which of the following pairs,each compound has same average oxidation state for A) S_(2)O_(3)^(2) and S_(4)O_(6)^(2-) (B) S_(2)O_(7)^(2-) and S_(2)O_(8)^(2-) (C) S_(4)O_(6)^(2-) and S_(2)O_(7)^(2-) (D) S_(4)O_(6)^(2-) and S_(2)O_(8)^(2-)

Estimation of oxidising substance involving the liberation of I_(2) and subsequent volumetric estimation of I_(2) are refferred to as 2Cu^(2+)+4I^(Theta)rarr Cu_(2)I_(2)+I_(2) I_(2)+ S_(2)O_(3)^(2-)rarr S_(4)O_(6)^(2-)+2I^(Theta)

VK JAISWAL ENGLISH-TYPES OF REACTIONS-SUBJECTIVE PROBLEMS
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  2. Find total number of reagnets which cann produce I(2) from KI solution...

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  3. Find total number of metal cations which are ppted as metal sulphide o...

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  4. Consider the following reaction P(4)+KOH to PH(3)+X How many P-H bon...

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  5. Which of the following species/reagent can reduce Fe^(3+)(aq.) into Fe...

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  6. Find out number ionic compounds which is/are water insoluble at room t...

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  7. Find the value of expression |x-y| for following compounds. where, ...

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  8. Find out total number of coloured compound(s) from following: BaCO(3...

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  9. Find out total number of cation(s) that produce precipitate with aqueo...

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  10. P(4)+SOCl(2) overset(Delta)toProducts Find out total number of non-p...

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  11. What is average oxidation state state of sulphur in product formed in ...

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  12. find out total number of coloured/black water insoluble compound(s) fr...

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  13. Find out total number of compounds which on heating undergo redox reac...

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  14. How many following Ammonium salts will evolve N(2) gas on heating? (...

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  15. How many following metals evolve NO (Nitric oxide) gas with dil. HNO(3...

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  16. Find number of basic radicals among the following cations, which can f...

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  17. Calculate difference between oxidation state of chromium (Cr) in blue ...

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  18. If hydrolysis of interhalogen compound can be represented by following...

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  19. Total number of species that can be oxidzed by acidic permanganate ion...

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  20. How many following metals evolve N(2)O gas with dil. HNO(3) (20%) Cr...

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  21. How many following ammonium salts will evolve NH(3) gas on heating? ...

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