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N(2)O(3) overset(R.T.) to NO+NO(2)...

`N_(2)O_(3) overset(R.T.) to NO+NO_(2)`

A

For disproportionation reaction.

B

For comproportionation reaction.

C

For either intermolecular redox reaction or displacement reaction

D

For either thermal combination redox reaction or thermal decomposition redox reaction.

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The correct Answer is:
To solve the question regarding the decomposition of \( N_2O_3 \) into \( NO \) and \( NO_2 \), we will follow these steps: ### Step-by-Step Solution: 1. **Identify the Reaction**: The reaction given is: \[ N_2O_3 \overset{(R.T.)}{\rightarrow} NO + NO_2 \] This indicates that \( N_2O_3 \) is breaking down into two products: nitric oxide (\( NO \)) and nitrogen dioxide (\( NO_2 \)). 2. **Classify the Reaction**: Since a single reactant (\( N_2O_3 \)) is decomposing into two products, this is classified as a **decomposition reaction**. 3. **Determine the Type of Decomposition**: The reaction occurs at room temperature (R.T.), which indicates that it is a **thermal decomposition reaction**. 4. **Analyze Oxidation States**: To further analyze the reaction, we need to determine the oxidation states of nitrogen in the reactants and products: - In \( N_2O_3 \): - Let the oxidation state of nitrogen be \( x \). - The equation for the oxidation state is: \[ 2x + 3(-2) = 0 \implies 2x - 6 = 0 \implies 2x = 6 \implies x = +3 \] So, nitrogen in \( N_2O_3 \) has an oxidation state of +3. - In \( NO \): - The oxidation state of nitrogen is +2 (since oxygen is -2). - In \( NO_2 \): - The oxidation state of nitrogen is +4 (since oxygen is -2). 5. **Identify Oxidation and Reduction**: - Nitrogen in \( N_2O_3 \) goes from +3 to +2 in \( NO \) (reduction). - Nitrogen in \( N_2O_3 \) goes from +3 to +4 in \( NO_2 \) (oxidation). - Since one species is oxidized and another is reduced, this is a **disproportionation reaction**. 6. **Conclusion**: The correct classifications for the reaction are: - It is a **decomposition reaction**. - It is also a **disproportionation reaction**. ### Final Answer: The reaction \( N_2O_3 \rightarrow NO + NO_2 \) is a **decomposition reaction** and a **disproportionation reaction**.
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VK JAISWAL ENGLISH-TYPES OF REACTIONS-SUBJECTIVE PROBLEMS
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