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NH(4)Cl+NaNO(2) overset(Delta)toN(2)uarr...

`NH_(4)Cl+NaNO_(2) overset(Delta)toN_(2)uarr+NaCl+H_(2)O`

A

For disproportionation reaction.

B

For comproportionation reaction.

C

For either intermolecular redox reaction or displacement reaction

D

For either thermal combination redox reaction or thermal decomposition redox reaction.

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The correct Answer is:
To determine the type of reaction represented by the equation: \[ \text{NH}_4\text{Cl} + \text{NaNO}_2 \xrightarrow{\Delta} \text{N}_2 + \text{NaCl} + \text{H}_2\text{O} \] we will analyze the oxidation states of the elements involved in the reactants and products. ### Step 1: Identify the oxidation states in the reactants 1. **For NH4Cl**: - NH4+ has a charge of +1. - Chlorine (Cl) has an oxidation state of -1. - Let the oxidation state of nitrogen in NH4+ be \( x \). - The equation for NH4+ is: \[ x + 4(-1) = +1 \implies x - 4 = 1 \implies x = +3 \] - Therefore, nitrogen in NH4Cl is in the -3 oxidation state. 2. **For NaNO2**: - Sodium (Na) has an oxidation state of +1. - Oxygen (O) has an oxidation state of -2. - Let the oxidation state of nitrogen in NaNO2 be \( y \). - The equation for NaNO2 is: \[ +1 + y + 2(-2) = 0 \implies y - 3 = 0 \implies y = +3 \] - Therefore, nitrogen in NaNO2 is in the +3 oxidation state. ### Step 2: Identify the oxidation states in the products 1. **For N2**: - Nitrogen in its elemental form (N2) has an oxidation state of 0. 2. **For NaCl**: - Sodium (Na) is +1 and Chlorine (Cl) is -1. 3. **For H2O**: - Hydrogen (H) is +1 and Oxygen (O) is -2. ### Step 3: Analyze the changes in oxidation states - In the reactants: - Nitrogen in NH4Cl is -3. - Nitrogen in NaNO2 is +3. - In the products: - Nitrogen in N2 is 0. ### Step 4: Determine the type of reaction - One nitrogen atom is oxidized from -3 to 0 (loss of electrons). - Another nitrogen atom is reduced from +3 to 0 (gain of electrons). This indicates that we have a situation where a single species (nitrogen) is present in two different oxidation states in the reactants, which is characteristic of a **comproportionation reaction**. ### Conclusion The type of reaction represented by the equation is a **comproportionation reaction**. ---
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Out of the following redox reactions I. NH_(4)NO_(3)overset(Delta ) ( rarr) N_(2)O + 2H_(2)O II. NH_(4)NO_(2) overset( Delta)(rarr)N_(2) + 2H_(2)O III. PCl_(5) overset(Delta ) ( rarr) PCl_(3) + Cl_(2) disproportionation is not shown in

In how many of the following reactions N_(2) gas may be released {:((a) NH_(4)NO_(2) overset(Delta)rarr,(b) (NH_(4))_(2) Cr_(2)O_(7) overset(Delta)rarr,(c) NH_(2)CONH_(2) + HNO_(2) overset(Delta)rarr),((d) NH_(2)CONH_(2) + NaOBr rarr,(e) NH_(3) + Cl_(2) (LR) rarr,(f) NH_(3) + Br_(2) (LR) rarr),((g) NH_(3) + NaOCl rarr,(h) NH_(3) + CaOCl_(2) rarr,(i) Ba(N_(3))_(2) overset(Delta) rarr):}

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